We consider the work of reversible mixing of ideal gases using a real process. New assumptions were made concerning infinite shifts, infinite number of cycles and infinite work to provide an accurate calculation of entropy resulting from reversible mixing of ideal gases. We derived an equation showing the dependence of this entropy on the difference in potential of mixed gases, which is evidenc...

one series of half-analogues of michler’s ketone containing one or more terminal methoxysubstituents with variable tertiary amino groups have been used in this study. nmr spectralresults for the parent ketones confirm earlier findings that ortho proton shifts are apparentlyindependent from steric effects in derivatives of michler’s ketone because the ring current andcarbonyl-induced shifts are ...

Suppressing Z2-monopoles shifts the line of deconfinement transitions in the coupling plane of the SU(2) lattice gauge theory with a mixed Villain form of action but it still continues to behave also like the bulk transition line. Separate deconfinement and bulk phase transitions are found on the same lattice, suggesting the two to be indeed coincident at higher adjoint couplings. Universality ...

Advanced spoken dialogue systems incorporate functionalities such as mixed-initiative and cross-domain dialogues. In this paper an object-based approach to cross domain dialogue modelling is described in which service agents representing primary transaction types and support agents representing tasks such as eliciting payment details are selected as appropriate by a domain spotter. The domain s...

abstract this paper attempts to re-investigate the catching-up (stochastic convergence) hypothesis among the selected 16 oecd countries applying the time series approach of convergence hypothesis with annual data over one century. to reach this aim, we propose a model which specifies a trend function, incorporating both types of structural breaks – that is, sharp breaks and smooth shifts using ...

Global climate shifts and ecological flexibility are two major factors that may affect rates of speciation and extinction across clades. Here, we connect past climate to changes in diet and diversification dynamics of ruminant mammals. Using novel versions of Multi-State Speciation and Extinction models, we explore the most likely scenarios for evolutionary transitions among diets in this clade...

nowadays nmr spectroscopy becomes a powerful tool in chemistry because of the nmr chemical shifts. hartree–fock theory and the gauge-including atomic orbital (giao) methods are used in the calculation of 29si nmr chemical shifts of various silicate species in the silicate solution as initial components for zeolite synthesis both in gas and solution phase. calculations have been performed at geo...

The 13C chemical shifts for a series of compounds which includes carboxylic acids, aldehydes, ethers, ketones and hydrocarbons were simulated by using the parametric techniques. The observed chemical shifts were related to numerically encoded structural parametes called descriptors. Two new electronic descriptors were added to the previous descriptors. Ploting of experimental ver...

We obtain a complete characterization for doubly commuting mixed invariant subspaces of the Hardy space over unit polydisc. say closed subspace Q H2(Dn) is if Mzj(Q)⊆Q 1≤j≤k and Mzj⁎(Q)⊆Q, k+1≤j≤n some integer k∈{1,2,…,n−1}. prove that only ifQ=ΘH2(Dk)⊗Qθ1⊗⋯⊗Qθn−k, where Θ∈H∞(Dk) inner function Qθj either Jordan block H2(D)⊖θjH2(D) θj or H2(D). Furthermore, an explicit representation commutant ...

in this paper we present a method for optimal design of combined ewma-ewma control scheme. shewhart control chart, introduced by walter shewhart, only takes into account present information of the process, so it is insensitive in detecting small shifts. ewma and cusum control charts are good choices for detecting small shifts. a combined control scheme monitors the process for large and small s...