In this work, we demonstrate the successful incorporation of pure fullerene from solution into two-dimensional layered aluminosilicate minerals. Pure fullerenes are insoluble in water and neutral in terms of charge, hence they cannot be introduced into the clay galleries by ion exchange or intercalation from water solution. To overcome this bottleneck, we organically modified the clay with quat...

Recently, Supercritical fluids have been used in material synthesis and processing because of their special properties such as high diffusivity, low viscosity, and low surface tension. Supercritical carbon dioxide is the most attractive because it is non-toxic, non-flammable, and has moderate critical temperature and critical pressure. Moreover, and can also swell most polymers. In this study, ...

Chemical modifications of clay to remove methylene blue (MB) from aqueous solutions at room temperature were compared. Natural bentonite (NC) was modified by cation exchange with hexadecyltrimethylammonium chloride (HC), bencyltriethylammonium chloride (BC), and tetramethylammonium chloride (TC) to reverse the surface polarity of the hydrophilic bentonite. The adsorption of MB was studied and f...

-Hydrothermal treatment of a mixture of silicic acid, cobalt chloride, sodium dithionite and sodium hydroxide at 250 ~ under 500 psi of argon produced a pink solid. X-ray powder diffraction (XRD), transmission electron microscopy (TEM) and electron diffraction data showed the product to be a well-crystallized smectite. SEM/EDX analysis gave a unit cell formula of [(Si8.05)(Co558)O20(OH)4]Na066....

Three different protocols for the preparation of polymer layered silicate nanocomposites based upon a tri-functional epoxy resin, triglycidyl para-amino phenol (TGAP), have been compared in respect of the cure kinetics, the nanostructure and their mechanical properties. The three preparation procedures involve 2 wt% and 5 wt% of organically modified montmorillonite (MMT), and are: isothermal cu...

The clay materials are distinguished on the basis of their different crystal structures. Due to their specific structure, they are applied in the nuclear industry for the removal of radionuclides from nuclear liquid waste as ion exchange material. This mini review presents some of the recent advances of various kinds of clay materials in this aspect. These inorganic materials continue to gain a...

Presence of heavy metal ions in wastewater is an important public concern. Adsorption are commonly used technique to remove various pollutants, including the ions, from contaminated water sources. However, common methods for adsorption are not completely efficient at low ion concentrations and the adsorbent should be improved in order to reaching the acceptable levels of adsorption efficiency. ...

this paper discusses about preparation of biodegradable polymer /clay nanocomposites based on organically modified montmorillonite clay; i.e. cloisite 10a and biodegradable polymer chitosan by solution mixing technique and their characterization. the nanocomposites were successfully prepared and their structures were characterized by powder x-ray diffraction (xrd), particle size analyzer (beckm...

Lateral pile response of the 3 × square group has been investigated in terms lateral displacement and maximum bending moment using three-dimensional finite element analysis. Soil is represented 8-node isoparametric elements. Piles cap are modelled 20-node The 16-node interface elements used to establish continuity between surrounding soil. by modified Cam clay criterion. entire code developed F...

In this paper, the performance of a gas barrier that consisted polyacrylamide (PAM)-modified compacted clayey soil was experimentally explored. The moisture content and water loss characteristics tested soils were adopted as indicative indices retention capacity (WRC). permeability (Kp) diffusion coefficient (Dp) modified clays evaluated via tests. test results showed clay samples subjected to ...