[MnIV3(micro-O)4(phen)4(H2O)2]4+ (, phen=1,10-phenanthroline) equilibrates with its conjugate base [Mn3(micro-O)4(phen)4(H2O)(OH)]3+ in aqueous solution. Among the several synthetic multinuclear oxo- and/or carboxylato bridged manganese complexes known to date containing metal-bound water, to the best of our knowledge, only deprotonates (right harpoon over left harpoon+H+, pKa=4.00 (+/-0.15) at...

Different structural chemistries resulting from the Pb2+ lone-pair electrons in the PbMO3 perovskites are reviewed. The Pb2+ lone-pair electrons enhance the ferroelectric transition temperature in PbTiO3, stabilize vanadyl formation in PbVO3, and induce a disproportionation reaction of CrIV in PbCrO3. A Pb2+ + NiIV = Pb4+ + NiII reaction in PbNiO3 stabilizes the LiNbO3 structure at ambient pres...

derivative3–6 (1) have been reported to have a greater tendency to yield polynuclear complexes. This communication presents the X-ray structure of the Ni–Mn–Ni complex (2) prepared using ligand 1 (Fig. 1). The title complex was prepared in two steps. Step 1: After the ligand (0.01 mol, 2.98 g) was dissolved in hot EtOH (50 mL), a solution of NiCl2·6H2O (0.01 mol, 2.37 g) in hot water (30 mL) an...

A room-temperature electrochemical strategy for hydrogenation (deuteration) and reverse dehydrogenation of N-heterocycles over a bifunctional MoNi4 electrode is developed, which includes the quinoxaline using H2O as hydrogen source with 80% Faradaic efficiency hydrogen-rich 1,2,3,4-tetrahydroquinoxaline up to 99% yield selectivity. The in situ generated active atom (H*) plausibly involved quino...

Hemophilia A is caused by a deficiency of actor-Vlll procoagulant (NIII) activity. The current treatment by frequent infusions of plasma-derived Nlll concentrates is very effective but has the risk of transmittance of blood-borne viruses (human immunodeficiency virus IHIVI, hepatitis viruses). Use of recombinant DNA-derived Nlll as well as gene therapy could make hemophilia treatment independen...

Reactions between K[TpFe(CN)3] (Tp- = hydrotris(1-pyrazolyl)borate) and M(ClO4)2 x 6H2O (M = Co or Ni) in a mixture of acetonitrile and methanol afford, upon crystallization via THF vapor diffusion, [Tp8(H2O)12Co6Fe8(CN)24](ClO4)4.12THF x 7H2O (1) and [Tp8(H2O)12Ni6Fe8(CN)24](ClO4)4.12THF x 7H2O (2). Both compounds contain cyano-bridged clusters with a face-centered cubic geometry, wherein octa...

Heterobimetallic NiZn complexes featuring metal centers in distinct coordination environments have been synthesized using diimine-dioxime ligands as binucleating scaffolds. A tetramethylfuran-containing ligand derivative enables a stable one-electron-reduced S = 1/2 species to be accessed using Cp2Co as a chemical reductant. The resulting pseudo-square planar complex exhibits spectroscopic and ...