it is very important to determine the stable nitrogen isotope ratio for the nitrogenous substances in aerosols and the geochemistry behavior of stable nitrate ion isotopes in aerosols in order to elucidate the chemical and physical functions of clouds. hence, aerosol field sampling was conducted in the skies offshore from malibu beach and santa barbara, california, u.s.a. on 16 and 18 july 2009...

Corresponding Author: Zhiwei Chen School of Life Sciences, Shandong University of Technology, 255049, Zibo, China Tel: +86-05332786781, Fax: +86-05332786781 Email: [email protected] Abstract: In this study, the anions nitrite ion (NO2 ) and nitrate ion (NO3 ) in celeries and carrots were detected with the technique of ion chromatography. A Dionex ICS-2000 ion chromatograph was used to detect the c...

Rapid separation and determination of mixtures of L-ascorbic acid, nitrite, sulfite, oxalate, iodide and thiosulfate by conventional ion chromatography is often difficult due to incomplete separation of L-ascorbic acid and nitrite from the water peak when using eluents giving short elution times for iodide and thiosulfate. Separation of the six species within about 15 min has been achieved by i...

Nitrite ion has been identified as the active ingredient of two commercial adulterants that could cause discrepant results between the immunoassay screening and gas chromatographic-mass spectrometric (GC-MS) confirmation of 11-nor-delta9-tetrahydrocannabinol-9-carboxylic acid (THCCOOH) in urine. Procedures to chemically convert the nitrite ion at the beginning of sample preparation for GC-MS an...

An iron oxide/reduced graphene oxide (ION-RGO) nanocomposite has been fabricated to functionalize a low-cost electrochemical nitrite sensor realized by light-scribed reduced (LRGO) electrodes on PET substrate. To enhance the stability and adhesion of electrode, substrate was modified RF oxygen plasma, thin layer cationic poly (diallyl dimethyl ammonium chloride) deposited. Raman spectroscopy sc...

A flow injection analysis system was built with a liquid core waveguide spectrophotometric detector using an 80 cm Teflon AF-1600 capillary tube (2,2-bistrifluoromethyl-4,5-difluoro-1,3-dioxole/tetrafluoroethylene). The system was applied to determine nitrite ion in river water samples. The lower limit of detection for nitrite was 2.1 nmol dm(-3) (0.1 ng dm(-3) as NO(2)(-)) and the relative sta...

The retention behavior of inorganic anions on a pyridine stationary phase commercially available for hydrophilic interaction chromatography was examined in ion chromatography. Inorganic anions were retained on a protonated pyridine stationary phase under acidic eluent conditions (pH 3.1-3.3) in the ion-exchange mode. The logarithm of the retention factor of analytes was linear to the logarithm ...

The gene encoding cytochrome c nitrite reductase (NrfA) from Desulfovibrio desulfuricans ATCC 27774 was sequenced and the crystal structure of the enzyme was determined to 2.3-A resolution. In comparison with homologous structures, it presents structural differences mainly located at the regions surrounding the putative substrate inlet and product outlet, and includes a well defined second calc...

We cloned a bacterial copper-containing nitrite reductase (NirK) homolog gene of Aspergillus oryzae (AonirK). Alignment showed that amino acid residues crucial for copper binding are conserved in the deduced sequence of the fungal protein. The recombinant protein exhibited distinct nitrite reductase activity, and its absorption and EPR spectra showed the presence of type 1 and type 2 copper ato...