We have performed a series of ab initio molecular orbital and molecular dynamics calculations to ascertain the influence of an endohedral noble gas atom on the reactivity of the surface of the model system C(70)O(3). Our simulations show that the minimum energy pathways for the ozone ring-opening reaction are influenced by the presence of the endohedral atom. The effect is isomer dependent, wit...

Low background miniaturized proportional counters as developed for the GALLEX solar neutrino experiment can be applied to the detection of radioactive noble gas nuclides at very low activities. We have developed an apparatus that allows the activity of trace amounts of isotopes of the four noble gases Ar, Kr, Xe and Rn to be measured. The technique includes contamination-free chromatographic pu...

Noble-transition metal (noble=Pt,Au; transition=Co,Ni,Cu) alloy particles with sizes of about 5 nm have been studied by in situ high-energy x-ray diffraction while subjected to oxidizing (O(2)) and reducing (H(2)) gas atmospheres at elevated temperatures. The different gas atmospheres do not affect substantially the random alloy, face-centered-cubic structure type of the particles but do affect...

zno and zno: mn nanocrystals were synthesized via reverse micelle method. the structural properties of nanocrystals were investigated by xrd. the xrd results indicated that the synthesized nanocrystals had a pure wurtzite (hexagonal phase) structure. resistive gas sensors were fabricated by providing ohmic contacts on the tablet obtained from compressed nanocrystals powder and the installation ...

in this study, a specific ch4 sensor is fabricated based on interdigitated electrode that modified with core-shell of tungsten carbide/tin oxide (wc/sno2) nanoparticles by wet chemical method in different percents of carbon and tungsten. the morphology of wet chemical-synthesized wc/sno2 core-shell was evaluated by different methods such as patterned x-ray diffraction (xrd), and particle size a...

Abnormal growth of population and development enormously increases energy demand. In present scenario utilization of fossils fuels to meet this demand is not enough and also leads to pollution, global warming, climate change as well as natural disaster. Therefore, hydrogen as energy carrier is a major option on these prospects as it is non-polluting and renewable. The renewable hydrogen energy ...

The double-bulb rubidium maser (DBRM) relies on a vacuum cell for its operation. This differs from the spin-exchange noble gas cells which contain Xe, He and N2 as well as rubidium. These gases (in addition to playing active roles in the noble gas experiments) act as a buffer, keeping the Rb away from the walls of the cell. In the DBRM the lack of buffer gases allows rubidium atoms to effuse be...