We investigate Li+ coordination in mixed electrolytes based on ionic liquids (ILs) and organic solvents and its relation with the macroscopic properties such as phase behaviour and ionic conductivity. Using Raman spectroscopy we determine the solvation shell around Li+ in mixtures formed by the IL N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide, the organic solvents ethylene ca...

a method based on the ultrasound-assisted solidification of floating drop microextraction technique was developed for the spectrophotometric and spectrofluorimetric determination of curcumin in turmeric powder. in this work a small volume of an organic solvent was floated on the surface of an aqueous solution. after sonication the organic solvent is solidified and separated. the effect of extra...

We report a visible-light-induced reductive decarboxylative C(sp(3))-C(sp) bond coupling reaction to construct aryl, alkyl and silyl substituted alkynes at room temperature in organic solvents or neutral aqueous solutions. This chemoselective alkynylation was compatible with various functional groups and biomolecules, and did not affect the protein enzyme activity.

The photophysical properties of a series of helicene cations in various solvents have been investigated using stationary and time-resolved spectroscopy. These compounds fluoresce in the near infrared region with a quantum yield ranging between 2 and 20% and a lifetime between 1 and 12 ns, depending of the solvent. No clear solvent dependence could be recognized except for a decrease of fluoresc...

Water-soluble TPPS was found to self-assemble into long nanofibers of ambiguous chirality in organic solvents, while mirror imaged chiroptical nanorods with controlled chirality were formed when (1R,2R)-(-)- or (1S,2S)-(+)-1,2-diaminocyclohexane was involved during the self-assembly.

This communication describes the use of a molecular hydrogel to immobilize enzymes for catalyzing reactions in an organic solvent to attain superactivity and exceptional stability.

The major components from Sappi Saiccor’s two bleaching streams of effluent were isolated and purified using chromatographic methods and characterised using NMR and other spectroscopic techniques. The major constituents extracted by organic solvents were identified as a sterol, fatty acids and lignin precursors and differ from the components identified in the pulping effluent stream.

Brine provides remarkable rate acceleration and a higher level of stereoselectivity over organic solvents, due to the hydrophobic hydration effect, in the enantioselective Michael addition reactions of 1,3-dicarbonyls to β-nitroolefins using chiral H-donors as organocatalysts.

A low-melting solid is used as organic solvent for liquid-liquid extraction at elevated temperatures followed by solidification and decantation of the aqueous phase.

In order to exploit fully the biotechnological opportunities afforded by nonaqueous enzymology, the issue of often drastically diminished enzymatic activity in organic solvents compared with that in water must be addressed and resolved. Recent studies have made great strides towards elucidating causes of this phenomenon of activity loss. None of these causes is insurmountable; by designing stra...