In this study, we aimed to enhance the catalytic activity of perovskite catalysts and elucidate their behavior in oxidative coupling methane (OCM), using alkali-added LaAlO3 catalysts. We prepared LaAlO3_XY (X = Li, Na, K, Y mol %) applied them OCM reaction. The results showed that catalysts’ activities were promoted compared catalyst. reaction, ethane was first synthesized through dimerization...