The sorption kinetics and thermodynamics of 1,3-dinitrobenzene (DNB), m-nitrotoluene (mNT), p-nitrophenol (pNP), and nitrobenzene (NB) on as-grown and nitric acid-oxidized multiwalled carbon nanotubes (MWCNTs) were investigated. The sorption kinetics was well described by a pseudo-second-order rate model, while both Langmuir and Freundlich models described the sorption isotherms well and the so...

The compound p-nitrophenol, which shows the anti-androgenic activity, can easily become anthropogenic pollutants and pose a threat to the environment and human health. Previous work indicates that the anti-androgenic mechanism of p-nitrophenol is complex and may involve several components in the AR signaling pathway, but the molecular details of how p-nitrophenol inhibits AR signaling are still...

Methyl parathion (MP), an organophosphate pesticide, was sprayed illegally for pest control in U.S. residences and businesses in Mississippi and Ohio. To evaluate the association between MP exposure and neurobehavioral development, children 6 years of age or younger at the time of the spraying and local comparison groups of unexposed children were assessed using the pediatric environmental neur...

Cover crops are promoted to increase soil organic carbon (SOC) storage and improve biological health in agricultural systems. However, cover crop effects on microbial communities – key regulators of SOC nutrients functioning not clear semiarid environments. This study investigated the response community structure enzyme activities integration under limited-irrigation winter wheat (Triticum aest...

A new, rapid, sensitive, selective and portable fluorescence detection method for nitroaromatics based on polymer dots (Pdots) had been successfully developed not only in aqueous media but also in the solid state with test strips. The fluorescence quenching rates were proportional to the concentrations of 2,4,6-trinitrophenol (TNP) in the range of 0.2-20.0 μg mL(-1) and p-nitrophenol (PNP) in t...

The superfamily of sulfotransferase (SULT) enzymes catalyzes the sulfate conjugation of several pharmacologically important endo- and xenobiotics. SULT1A1 catalyzes the sulfation of small planar phenols such as neurotransmitters, steroid hormones, acetaminophen, and p-nitrophenol (PNP). Genetic polymorphisms in the human SULT1A1 gene define three alleles, SULT1A1*1, *2, and *3. The enzyme activ...

Liver microsomal cytochrome P4502E1-dependent p-nitrophenol (PNP) hydroxylation and expression of cytochrome P4502E1 were studied in rats subjected to gamma-hexachlorocyclohexane (HCCH) or L-3,3,5-triiodothyronine (T3) administration as a possible mechanism contributing to superoxide radical (O2.-) generation. HCCH treatment (a single dose of 40 mg/kg body wt) produced a 43% increase in the con...

1,1-Dichloroethylene (DCE) exposure evokes lung toxicity with selective damage to bronchiolar Clara cells. Recent in vitro studies have implicated CYP2E1 and CYP2F2 in the bioactivation of DCE to 2-S-glutathionyl acetate [C], a putative conjugate of DCE epoxide with glutathione. An objective of this study was to test the hypothesis that bioactivation of DCE is catalyzed by both CYP2E1 and CYP2F...

Three Ag nanoparticle (NP) colloids are produced from borohydride reduction of silver nitrate in water by varying the amount sodium citrate. These nanoparticles used as photocatalysts with H2O2 to degrade a p-nitrophenol (PNP) solution. X-ray diffraction patterns have shown production metallic nanoparticles, whatever concentration The transmission electron microscope images these NPs highlighte...