The toxicity and corrosion potential of hydrogen sulfide in raw biogas underlines the need for biogas purification. Several techniques available for removal of hydrogen sulfide from biogas are out of the reach for common end users due to lack of knowledge, higher running costs, and insufficient operational skills. The present experimental study aims to propagate hydrogen sulfide removal techniq...

The aim of this study is to evaluate the biodegradation performance of phenol in a fixed biofilm developed in sand soil media. The parameters which had been studied and may influence the biodegradation were: a) the grain size of sand, b) the rate of flow, and c) the initial phenol loading. Laboratory scale of two columns with inner diameter of 5 cm was used. The first column was packed with fin...

Monolithic columns are gaining interest as excellent substitutes to conventional particle-packed columns. These columns show higher permeability and lower flow resistance than conventional liquid chromatography columns, providing high-throughput performance, resolution and separation in short run times. Monoliths possess also great potential for the clean-up and preparation of complex mixtures....

Duplex capillary columns, the standard for electrochromatography using optical detection, consist of a packed and an open section. Normally, optical detection is performed in an on-column manner, i.e. at a point right after the packed section. It was deemed that band broadening may take place when an analyte band travels from the packed bed, through the frit and down to the open section. In thi...

Foaming can be a serious problem in the process industry. For packed columns foaming is often reported for treatments of sour gases with alkaline solutions (e.g. amine scrubbing), but also for distillation and extractive distillation. Existing hydrodynamic prediction methods for pressure drop and flood points, but also for mass transfer efficiencies, do not consider foaminess. To build an exper...

In recent decades packed columns have become very popular for distillation processes since they acquire higher loadings and a better separation efficiency than ordinary tray columns. Fluid dynamics cover an important place in the design of packed towers. Identifying the main quantities remains subject of various research works. There exists a wide range of different approaches to determine the ...

In this work a new mathematical model, based on non-equilibrium conditions, describing the dynamic adsorption of proteins in columns packed with spherical adsorbent particles is used to study the performance of chromatographic systems. Simulations of frontal chromatography, including axial dispersion, for non-equilibrium systems with non-linear adsorption isotherms are made and compared to thos...

Rolled, continuous stationary phases were constructed by tightly rolling and inserting a whole textile fabric into a chromatography column. This work reports the column performance, in terms of plate height, void fraction, and resolution, of 10 cellulose-based fabrics. The relation between fabric structural properties of yarn diameter, fabric count, fabric compressibility, and column performanc...

The retention behavior of large polycyclic aromatic hydrocarbons (LPAHs) (> or = 7 rings) on newly developed metalloplotoporphyrin (MProP)-silica stationary phases is examined and the results are compared to previously reported data for retention of the same solutes on commercially available phases. HPLC columns packed with FeProP-silica are shown to exhibit unique shape selectivity for LPAH re...

Wall-coated open-tubular (WCOT) columns provide higher column efficiency and lower solute interfacial adsorption effect than packed columns. However, previous efforts used to measure the infinite dilution activity coefficient (γ(∞)) via a chromatographic technique have used packed columns, because the low carrier gas flow rate (U) and the small stationary phase amount (n(2)) in WCOT columns rai...