Molecular Trapping In article number 2203745, Jingui Duan, Susumu Kitagawa, and co-workers report a trap-and-flow channel crystal, where the flow provides an effective shape- size-dependent sieving path for linear acetylene carbon dioxide, while possesses customized space of efficient molecular trapping, yielding record productivity poly-grade C2H4 from C2H2/CO2/C2H4 mixtures.