ZnO and SnO2-doped ZnO nanoparticles were prepared by a sol–gel method for the first time. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the ZnO and SnO2-doped ZnO samples. Advanced oxidation processes (AOPs) have proved very effective in treatment of the various hazardous organic pollutants such as surfactants and pharmaceuticals...

Several homogeneous photo-based advanced oxidation processes-namely photolysis, photo-oxidation, and photo-Fenton oxidation—were investigated for the elimination of ibuprofen in water. The effects several operating parameters, such as lamp type (low or medium pressure mercury, xenon-arc), concentration hydrogen peroxide (0.5 to 7 times stoichiometric amount required mineralization), Fenton reag...

Various chromium-containing catalysts were tested for the total oxidation of trichloroethylene (TCE) as a model reaction for the catalytic combustion of chlorinated organic pollutants. A spinel-type cobalt chromite (CoCr2O4) among others was proven to be a very promising catalyst showing higher activity and higher CO2 selectivity than traditional alumina supported chromia. Even if both Cr3+ and...

i Preface The report deals with development of reduced kinetic mechanisms for ammonia oxidation that can be used for CFD modeling of NO x formation in biomass combustors. A computer code CARM was tested for generation of the reduced mechanisms. Berkeley. We want to thank him for supplying us with the code, as well as helping us to get started. The report firstly describes shortly the general me...

Landfill leachates are a mixture of high concentration organic and inorganic contaminants need to be appropriately treated due their toxicity severe adverse effects on the environment. Here, we studied treatment landfill leachate through heterogeneous Fenton-like oxidation process using zirconia supported copper catalyst (Cu/ZrO2). Reaction conditions such as pH, amount catalyst, oxidant dose, ...

ABSTRACT A program is developed that includes two hydrodynamic models, a 2D depth-averaged (2DH) and a Quasi-3D (Q3D), and a pollutant transport model that uses a 1 order upwinding and a 3 order QUICKEST numerical schemes. Several tests were performed in two test basins in order to examine the performance of the above models. The Q3D model is successfully applied to Lake Ontario, using a 4-km-s...

In a continuing effort to analyze the selectivity/redundancy of the three glutaredoxin (Grx) enzymes of the model cyanobacterium Synechocystis PCC6803, we have characterized an enzyme system that plays a crucial role in protection against two toxic metal pollutants, mercury and uranium. The present data show that Grx1 (Slr1562 in CyanoBase) selectively interacts with the presumptive mercuric re...

The College of Engineering, Center for Environmental Research and Technology (CE-CERT) at the University of California (UCR) is undertaking a new project to develop a “Next Generation” environmental chamber for evaluating chemical mechanisms under lower pollutant conditions than has previously been possible (Carter et al., 1999). A major objective of this project is to generate mechanism evalua...

Sequential reduction of chromate and nitrate, two competitive electron acceptors, has been demonstrated for strains of Pseudomonas genus for both planktonic cells and cells immobilised in agar layers on the surface of synthetic membrane. Denitrification occurs practically after chromate depletion. This order of reduction process is consistent with redox potentials of the respective reactions. I...

Humic acids (HA) are ubiquitous redox-active compounds of natural aquatic and soil systems. Here we studied the potential of HA as reductants for chlorinated aliphatic pollutants. To avoid artifacts potentially involved when studying chemically reduced HA, we prepared electrochemically reduced soil, aquatic and synthetic HA, and anthrahydroquinone-2,6-disulfonic acid (AHQDS), a model compound f...