نتایج جستجو برای: polymer supported catalyst

تعداد نتایج: 324270  

2001
Ju Yong Kim Kyu Yong Choi

In a gas phase %uidized bed ole)n polymerization reactor, it is generally assumed that polymer particles are well mixed and near isothermal reaction conditions prevail. When a highly active Ziegler–Natta catalyst or other type of high activity supported catalyst is used in a gas phase %uidized bed reactor, a certain heterogeneity in the polymer properties is often observed in di4erent size part...

Journal: :علوم و تکنولوژی پلیمر 0
مهدی سلامی کلجاهی وحید حدادی اصل محمد نجفی

in the present work, a titanium-based ziegler-natta catalyst was employed to synthesize ultra molecular weight polyethylene in a slurry medium. the effect of different parameters such as ethylene pressure, temperature, catalyst composition, and hydrogen pressure was studied. as the results indicate, increasing either [al]/[ti] ratio or temperature causes polymerization rate to go through a maxi...

Journal: :Chemical communications 2009
Sung Hun Youk Sang Ho Oh Ho Sik Rho Je Eun Lee Ji Woong Lee Choong Eui Song

The design, synthesis, and catalytic application of a highly enantioselective and indefinitely stable polymer-supported Cinchona-based bifunctional sulfonamide is reported.

Journal: :Journal of the American Chemical Society 2009
Yan Xia Andrew J Boydston Yefeng Yao Julia A Kornfield Irina A Gorodetskaya Hans W Spiess Robert H Grubbs

Ring-expansion metathesis polymerization (REMP) mediated by recently developed cyclic Ru catalysts has been studied in detail with a focus on the polymer products obtained under varied reaction conditions and catalyst architectures. Depending upon the nature of the catalyst structure, two distinct molecular weight evolutions were observed. Polymerization conducted with catalysts bearing six-car...

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