Xerogels and porous materials for specific applications such as catalyst supports, CO2 capture, pollutant adsorption and selective membrane design require fine control of pore structure, which in turn requires improved understanding of the chemistry and physics of growth, aggregation and gelation processes governing nanostructure formation in these materials. We used time-resolved dynamic light...

Kashmir is located in a region where winter temperatures are very low. During the winter months, the temperature in Kashmir is often below 0⁰ C. Generally concrete placed in colder regions with the help of insulated forms as well as heaters to protect freshly mixed concrete against freezing. These practices try to incorporate unnecessary carbon and leads to an disagreeable carbon footprint. The...

The anticipated worldwide increase in biodiesel production will result in an accumulation of glycerol for which there are insufficient conventional uses. The surplus of this by-product has increased rapidly during the last decade, prompting a search for new glycerol applications. We describe here the synthesis of dissymmetric chlorohydrin esters from symmetric 1,3-dichloro-2-propyl esters obtai...

We have developed "high-performance" liquid-chromatographic methods for determining 4-aminopyridine, an acetylcholine-releasing drug, in serum, saliva, and urine. As little as 1 microgram/L can be detected by extracting the alkalinized sample plus the internal standard (3,4-diaminopyridine) into dichloromethane, mixing the organic phase with 1-pentanol, evaporating the dichloromethane, and inje...

Solid sorbents based on lithium orthosilicate (Li4SiO4) have shown promise for CO2 capture at high temperature. Improved sorption properties can be obtained by appropriate doping. In this study, different promoted Li4SiO4-based sorbents were prepared by addition of potassium carbonate and binary/ternary alkali (Li, K and Na) carbonate eutectic mixtures. The CO2 sorption properties of the sorben...