نتایج جستجو برای: propargylic alcohols

تعداد نتایج: 11787  

2014
Yuan Zou Fu-Lin Zhu Zheng-Chao Duan Ya-Hui Wang De-Yang Zhang Zhong Cao Zhuo Zheng Xiang-Ping Hu

A copper-catalyzed asymmetric propargylic amination with a chiral ketimine P,N,N-ligand that proceeds via decarboxylation of propargyl carbamates has been developed. The reaction can be performed under the mild condition for a broad range of substrates, providing the corresponding propargylic amines in high yields and with up to 97% ee. This reaction represents a new and facile access to optica...

Journal: :Accounts of chemical research 2014
Benito Alcaide Pedro Almendros

Although gold is chemically inert as a bulk metal, the landmark discovery that gold nanoparticles can be effective catalysts has opened up new and exciting research opportunities in the field. In recent years, there has been growth in the number of reactions catalyzed by gold complexes [gold(I) and gold(III)], usually as homogeneous catalysts, because they are soft Lewis acids. In addition, alk...

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