Rechargeable proton-exchange membrane batteries that employ organic chemical hydrides as hydrogen-storage media have the potential to serve as next-generation power sources; however, significant challenges remain regarding the improvement of the reversible hydrogen-storage capacity. Here, we address this challenge through the use of metal-ion redox couples as energy carriers for battery operati...

Hybrid polymer electrolyte fuel cells combine a proton exchange membrane PEM and anion exchange membrane AEM and exhibit unique advantages. The electrochemical performance and current limitations of a hybrid cell with an alkaline electrode fabricated on a Nafion membrane was characterized at 70°C as a function of relative humidity. To separate the individual characteristics of the AEM anode and...

Reducing the operating temperature in the 500-750 °C range is needed for widespread use of solid oxide fuel cells (SOFCs). Proton-conducting oxides are gaining wide interest as electrolyte materials for this aim. We report the fabrication of BaZr(0.8)Y(0.2)O(3-δ) (BZY) proton-conducting electrolyte thin films by pulsed laser deposition on different single-crystalline substrates. Highly textured...

This article has been written for students and teachers of the science technology low-temperature fuel cells, as well scientists engineers actively involved in research development this area. It offers first an analysis cell electrocatalytic processes, identifying a common pattern mechanisms these processes which serves basis universal expression describing non-linear V vs log J dependences obs...

A new measuring method is described for obtaining a proton titration curve. The curve is obtained from a microporous composite membrane, consisting of polystyrene beads in an agarose matrix, with lysozyme molecules adsorbed to the bead surface. The membrane is incorporated into a sensor system by deposition on a silicon chip with a pH-sensitive ion-sensitive field effect transistor (ISFET) loca...

The high methanol crossover and high cost of Nafion® membrane are the major challenges for direct methanol fuel cell application. With the aim of solving these problems, a non-Nafion polymer electrolyte membrane with low methanol permeability and high proton conductivity based on the sodium alginate (SA) polymer as the matrix and sulfonated graphene oxide (SGO) as an inorganic filler (0.02-0.2 ...

Abstract Micropatterns applied to proton exchange membranes can improve the performance of polymer electrolyte fuel cells; however, mechanism underlying this improvement is yet be clarified. In study, a patterned membrane electrode assembly (MEA) was compared with flat one using electrochemical impedance spectroscopy and distribution relaxation time analysis. The micropattern positively affects...