monte carlo method is a very accurate method to optimize medical diagnostic radiology spectra and simulation of radiation transportation. using mcnp code, radiology and mammography attenuated x-rayspectraweresimulated.the ipem report number 78 was used as a reference to compare with the geant4 and mcnp simulations because of its popularity and wide availability. the results of geant4 in 40kev s...

Two new Cr(III) complexes based on 2-substituted 8-hydroxyquinoline ligands, namely [Cr(L₁)₃] (1), (HL₁=(E)-2-[2-(4-nitro-phenyl)-vinyl]-8-hydroxy-quinoline) and [Cr(L₂)₃] (2), (HL₂=(E)-2-[2-(4-chloro-phenyl)vinyl]-8-hydroxy-quinoline), were prepared by a facile hydrothermal method and characterized thoroughly by single crystal X-ray diffraction, powder X-ray diffraction, FTIR, TGA, ESI-MS, UV-...

In This research, gold nanoparticles were synthesized and functionalized by the antibody of aflatoxins. The quenching of the fluorescence of excitation emission matrices (EEM) of two type of aflatoxins (B1, G1), provoked by the gold nanoparticles, was studied by principal component analysis (PCA) and multivariate curve resolution with alternating least squares (MCR-ALS). These aflatoxins show q...

The first Mn L-edge absorption spectra of a Mn metalloprotein are presented in this paper. Both reduced and superoxidized Mn catalase have been examined by fluorescence-detected soft X-ray absorption spectroscopy, and their Mn L-edge spectra are dramatically different. The spectrum of reduced Mn(II)Mn(II) catalase has been interpreted by ligand field atomic multiplet calculations and by compari...

X-ray absorption near-edge structure (XANES) spectra for trace amount of Eu (<1 mg/kg) in natural samples were determined fluorescence mode using a Bragg-type crystal analyzer system. Effective separation Lα and Mn Kα emissions by the system allowed us to measure XANES with high sensitivity. Sharpening peak suppression inner-shell lifetime-broadening effect energy resolution detection (HERFD) a...

X-ray spectroscopy of Seyfert 2 galaxies provides an excellent probe of the circumnuclear environment in active galactic nuclei. The grating experiments on both Chandra and XMM-Newton have now provided the first high resolution spectra of several of the brightest Seyfert 2's. We present Chandra HETG data on Markarian 3, and XMM-Newton RGS data on NGC 1068. In both cases, the spectra are dominat...

A luminescent multilayer film has been fabricated from the polyoxometalate anion α[PMo12O40]3− (α-PMo12) and the cation Fuchsin Basic (FB) through an electrostatic layer-by-layer (LbL) self-assembly method and characterized by UV/Vis spectra, atomic force microscopy and X-ray photoelectron spectra. The fluorescence properties of the LbL film have also been investigated. Cyclic voltammetry measu...

Zinc lithium bismuth borate glasses containing Er in (25x): Bi2O3:20Li2O:20ZnO: 35B2O3:xEr2O3 (where x=1, 1.5,2 mol %) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by x-ray diffraction studies. Optical absorption and fluorescence spectra were recorded at room temperature for all glass samples. Judd-Ofelt intensity parameters Ωλ (λ=2, 4, 6) are e...

A facile synthesis of mercaptanacid-capped CdTe/CdSe (core/shell) type II quantum dots in aqueous solution by means of a microwave-assisted approach is reported. The results of X-ray diffraction and high-resolution transmission electron microscopy revealed that the as-prepared CdTe/CdSe quantum dots had a core/shell structure with high crystallinity. The core/shell quantum dots exhibit tunable ...