Sulfuric acid {[3-(3-silicapropyl)sulfanyl]propyl}ester (SASPSPE) is employed as a recyclable catalyst for the synthesis of α-amino nitriles. These syntheses were performed via a one-pot three-component condensation of aldehydes, amines, and trimethylsilyl cyanide under mild reaction conditions at room temperature. The catalyst could be recycled and reused several times without any loss of effi...

a simple and efficient method for the chemoselective 1,1-diacetate protection of aromatic aldehydes with acetic anhydride by using ni2+ supported on hydroxyapatite-core-shell magnetic γ-fe2o3 nanoparticles (γ-fe2o3@hap-ni2+) under solvent free conditions. this method has several advantages, including high yield, short reaction time, simple work-up and recyclable property of the catalyst. the ca...

PEG-embedded potassium tribromide ([K(+)PEG]Br(3) (-)) was found to be an efficient and recyclable catalyst for the synthesis of functionalized piperidines in high yields in a one step, three component coupling between aldehyde, amine and β-keto ester. At the end of the reaction the [K(+)PEG]Br(3) (-) was readily regenerated from the reaction mixture by treating the residue containing [K(+)PEG]...

Poly(4-vinylpyridine)-supported copper iodide nanoparticles is reported as a new, green and recyclable catalyst for the synthesis of aryl-14H-dibenzo [a-o] xanthenes under solvent-free conditions. This catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any loss of their efficiency.

CuO-CeO2 nanocomposite is reported as a green and highly efficient recyclable catalyst for the multicomponent  synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones under solvent-free conditions. The catalyst was synthesized by co-precipitation method and characterized by XRD, BET specific surface area, FESEM and EDS analysis.

A simple deep eutectic solvent based on tin (II) chloride was used as a dual catalyst and environmentally benign reaction medium for an efficient synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives, from aromatic and aliphatic aldehydes, 1,3-dicarbonyl compounds, and urea in good-to-excellent yields and short reaction time. This simple ammonium deep eutectic solvent, easily synthesized from...

The Knoevenagel condensation reaction of aldehydes with malononitrile was described in this study, which was catalyzed by an efficient and recyclable ionic liquid-supported proline. The method represented an attractive alternative to the classical synthesis strategies and exhibited the advantage of performing homogeneous chemistry on a large scale additionally avoided large excesses of reagents...

In this research, we have developed cheap recyclable and task-specific acidic ionic liquids (AILs) 1-hydrogen-3-methylimidazolium hydrogen sulfate [Hmim]HSO4, 1-hydrogen-3-methylimidazolium chloride [Hmim]Cl, 2-pyrrolidonium hydrogensulfate [Hnhp]HSO4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. The products coul...

Herein, a practical and mild method for the deoxygenation of a wide range of benzylic aldehydes and ketones is described, which utilizes heterogeneous Pd/C as the catalyst together with the green hydride source, polymethylhydrosiloxane. The developed catalytic protocol is scalable and robust, as exemplified by the deoxygenation of ethyl vanillin, which was performed on a 30 mmol scale in an ope...

N,N-diethylethanaminium-2-(sulfooxy) ethyl sulfate was synthesized and used as  an efficient, green, and recyclable catalyst and solvent for the nitration of aromatic compounds by nitric acid at 80oC