Graft copolymerization of acryl-amide onto guar-gum has been carried out in the presence of potassium per sulphate as a redox initiator. The prepared graft copolymer was characterized by various techniques such as FT-IR, SEMEDX and TGA-DTA-DTG. Activated charcoal was also studied as the adsorbent in the present study to evaluate their adsorption capacity for Cr (Vl) and compared it with indigen...

cylindrical thin-walled tubes due to construction and easy installation, high energy absorption capacity are used in the automotive industry as an impact energy absorber. however, the main weakness of cylindrical tubes is in the high initial peak load. therefore, in this paper, to overcome this weakness, a buckling initiator is used at the top of the tube. this buckling initiator is a steel rod...

The very fast calculation procedure described earlier is applied to calculate the titration curves of complicated redox systems. The theory is extended slightly to cover inhomogeneous redox systems. Titrations of iodine or 2,6-dichloroindophenol with ascorbic acid are described. It is shown that correspondence between theory and practice is good as long as the relevant stability constants and r...

Dr. Arne Holmgren (Ph.D., 1968) is recognized here as a redox pioneer, because he has published at least one article on redox biology that has been cited over 1000 times and has published at least 10 articles, each cited over 100 times. He is widely known for his seminal discoveries and in-depth studies of thioredoxins, thioredoxin reductases, and glutaredoxins. Dr. Holmgren, active throughout ...

increasing the thermal stability and resistance to bacterial attack (bioresistance) of the potato starch used in the water-based drilling fluid is the aim of this work. four types of potato starch grafted with acrylamide and a mixture of each one with acrylic acid, 2-acrylamido-2-methyl-1-propane sulfuric acid and itaconic acid were synthesized by manganese (iv)-induced redox system at the suit...

The Trx (thioredoxin) and Grx (glutaredoxin) systems control cellular redox potential, keeping a reducing thiol-rich intracellular state, which on generation of reactive oxygen species signals through thiol redox control mechanisms. Here, we give a brief overview of the human Trx and Grx systems. The main part focuses on our current knowledge about mitochondrial Grx2, which facilitates mitochon...

The bimetallic compound Na[W2(μ-Cl)3Cl4(THF)2]·(THF)₃ (1, {W (3) W}(6+), a'2e'4) is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and some of its derivatives. In most cases, addition of phenylacetylene (PA) as co-initiator improves the catalytic activity and retains the high cis-stereoselectivity. On the other hand, 1 can pol...

Graft copolymers of acrylamide on carboxymethyl cellulose (d.s 0.4-0.5) were prepared by the use of ceric ion, ceric ion/reductant molecule initiator systems in aqueous medium. The graft copolymers were characterized by IR spectroscopy. The extent of graft copolymerisation was measured in terms of grafted chains as a function of both ceric ion and ceric ion/reductant molecule concentrations. It...