The sonication of ionic organic liquids leads to decomposition of the liquids. Multibubble sonoluminescence spectra and headgas analysis reveal a variety of decomposition products from the sonolysis of N,N'-dialkylimidazolium ionic liquids. The decomposition is a result of acoustic cavitation, which generates localized hot spots from the implosive collapse of bubbles in the ionic liquids. Despi...

Research in room-temperature ionic liquids (RTILs) has exploded in the last two decades, which are marked by an exponential increase in the number of theoretical and experimental publications in this field. The typically good thermal stability, ionic conductivity, and solvability of RTILs make them superior electrolytes in many electrochemical applications, such as metal electrodeposition and e...

Ionic liquids (ILs) are largely made of ions and short-lived ion pairs. These often possess a unique combination of physical and chemical properties which are not available with molecular solvents. ILs are dynamic, attractive and rich research area and are gaining considerable attention as promising molten materials for a variety of applications in pharmaceutical and biotechnology fields. Ionic...

In this article, we describe general trends to be expected at short times when an excess electron is generated or injected in different room-temperature ionic liquids (RTILs). Perhaps surprisingly, the excess electron does not localize systematically on the positively charged cations. Rather, the excess charge localization pattern is determined by the cation and anion HOMO/LUMO gaps and, more i...