Selection of mobile phases markedly affect separation efficiency of eluted probes in gas chromatography (GC), the mobile phases have a pronounced effect on the retention times and efficiency of natural gas separation. In solid chromatography, carrier gases which are adsorbed to any extent occupy more active adsorption sites, reducing the net heat of adsorption of the eluted zone. The efficiency...

PURPOSE Indapamide is probably the most frequently prescribed diuretic drug, generally being used for the treatment of hypertension. It contains a chiral center in its molecule; is marketed as a racemic mixture; but there are rather few studies regarding the pharmacokinetic and the pharmacological effect differences of the two enantiomers. Our aim was the development of a simple, rapid and prec...

Capillary electrophoresis is a powerful separation technique that can achieve high efficiency separations of charged analytes. However, one limitation of capillary electrophoresis is the adsorption of cationic proteins and peptides onto the inner surface of the capillary wall, due to the negatively charged silanol groups on the bare fused silica capillaries. This can lead to poor separation eff...

Traditional dry magnetic separation has poor efficiency for fine-grained materials, and combining airflow a field may be one of the most effective means to improve it. Based on pneumatic drum separator developed by our team, an improved with segmented flow is proposed, which pushes materials move along surface. Analysis in zone forces particles show that makes it easier collect fine particles, ...

A simple and rapid capillary zone electrophoretic (CZE) method has been established for separation and quantification of a mixture of eight cephalosporins – cefadroxil (CFL), cefixime (CIX), cefuroxime sodium (CFR), ceftriaxone sodium (CTR), ceftizoxime (CFT), cefaclor (CFC), cefradine (CFD), and cefotoxime (CTA). Conditions affecting the separation were pH, buffer concentration, and applied po...

The present work is aimed at investigating the influence of the background electrolyte composition and concentration on the separation efficiency and resolution and mass spectrometric detection of illicit drugs in a capillary zone electrophoresis-electrospray ionization-time of flight mass spectrometry (CZE-ESI-TOF MS) system. The effect of phosphate, borate and Tris buffers on the separation a...

A method of separation and determination of homovanillic acid (HVA) and vanillylmandelic acid (VMA) was developed based on capillary zone electrophoresis/amperometric detection with high sensitivity, good resolution and selectivity. In order to achieve complete separation and good response, several factors including pH, buffer concentration, separation voltage, detection potential and the lengt...

Turbulent flow separation coupling heat transfer with the solid case in the high area ratio rocket nozzle is simulated with the CFD method and the results are investigated experimentally. The finite volume method, the 2nd order upwind scheme, SST k-ω turbulence model and enhanced wall function are employed to solve the N-S equation and thermal conduction equation. To predict the fluid field and...