A slight excess of silyl trifluoromethanesulfonate mediates a tandem enol silane formation-Mukaiyama aldol reaction in the presence of Hunig’s base. Preformation of the enol silane is unnecessary for efficient reactions, which proceed in 75-97% yield for the addition of aryl methyl ketones and acetate esters to non-enolizable aldehydes. Mechanistic data suggests that free amine is crucial for f...

Adhesion between the polymer matrix and fillers is an important factor influencing properties of obtained composites. One way to improve interactions at interface modify filler with coupling agents, e.g., silanes. The article presents effect modifying surface mineral a new type silane [triethoxy(ketoimino)silane] on mechanical polyester resin based Composites triethoxy(ketoimino)silane-modified...

BACKGROUND Molar bonding procedures need continuous improvement to be widely accepted clinically and eventually replace molar bands. MATERIAL AND METHODS The purpose of this study was to determine the effects of enamel micro-abrasion and silane coating of the base of molar tubes on shear and tensile bond strengths of orthodontic molar tubes. A total of 200 third molars were randomly allocated...

OBJECTIVES To evaluate the effect of different silane agents and air-drying temperatures on bond strength of translucent quartz fibre posts to composite resin. METHODS The post surface was etched with 10 vol% hydrogen peroxide for 20 min. A two-liquid coupling agent containing 4-methacryolxyethyl trimellitate anhydride (4-META) and gamma-trimethoxysilyil propyl methacrylate (gamma-MPTS) and t...

The aim of this study was to evaluate the influence of ceramic surface treatments and silane drying temperature on the microtensile bond strength (µTBS) of a resin composite to a lithium disilicate ceramic. Twenty blocks (7x7x5 mm) of lithium disilicate-based hot-pressed ceramic were fabricated and randomly divided into 4 groups: G1: acid etching with 9.5% hydrofluoric acid for 20 s and drying ...

OBJECTIVE To evaluate the effect of five experimental silane monomer primers in vitro on the shear bond strength of a phosphate ester resin-composite cement bonded to a silicatized zirconia framework. METHODS A total of 144 planar zirconia (Procera AllZircon) specimens were subjected to tribochemical silica treatment, randomly divided into 12 sub-groups (n=12), and silanized with 1.0%(v/v) ac...

in this research, effects of concentration and time of silane treatment of rice straw flour on the morphology and mechanical strengths of rice straw flour/polypropylene composites were investigated. tri ethoxy vinyl silane (c8h18o3si) with 98% purity in two concentrations of 5 and 10%, that each concentration had two immersion times including, 45 and 90 min for using treatment rice straw flour....

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Introduction: The selection of porcelain is based on high biocompatibility, endurance, superficial texture and aesthetics. Nevertheless, the innate fracture charateritics of porcelain is the main cause of the intra oral fractures. Electing a suitable porcelain restorative system in terms of stability of color is important. For this reason, this study aimed to examine the color changes of common...

titanium dioxide (tio2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization   in the presence of 3-aminopropyl triethoxy silane (aptes) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy  as a initiator. first, the initiator for nmrp was covalently bonded onto the surface of titanium dioxide na...