Mesoporous ZnS nanospheres is a novel heterogeneous catalyst for synthesis of 5-substituted 1H-tetrazoles from various nitriles and sodium azide with excellent catalytic performance.

It is shown that various substrates accelerate the disappearance of an adaptive enzyme when its own substrate has been removed from the medium. The order of effectiveness of such substrates appears to be connected with their chemical similarity to the adaptive substrate. It is shown that two conditions which are able to inhibit the formation of adaptive enzymes-anaerobiosis and the presence of ...

An expedient synthesis of N-unsubstituted 1,2,3-triazole-4-carboxylates has been demonstrated through [3 + 2] cycloaddition of sodium azide with α-haloacrylates. The process is highly reliable and exhibits an unusually wide scope with respect to α-fluoro-, α-chloro-, α-bromo-, and α-iodoacrylates. The potential of selected 1,2,3-triazole-4-carboxylates in the preparation of 1,5-dihydro-4H-[1,2,...

In the title compound, [Ni(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Ni(II) atom lies on an inversion center and adopts a distorted trans-NiO(2)N(4) octa-hedral geometry, coordinated by two N,O-bidentate 4,4,5,5-tetra-methyl-2-(5-methyl-imidazol-4-yl)-2-imidazoline-1-oxyl 3-oxide nitronyl nitroxide radical ligands and two monodentate azide anions.

A new polymeric copper complex, viz. catena-poly[[[mu-N,N'-bis(3-aminopropyl)oxamidato-kappa6N,N',O:N",N"',O']dicopper(II)]-di-mu-dicyanamido-1:1'kappa2N1:N5;2:2'kappa2N1:N5], [Cu2(C8H16N4O2)(C2N3)2]n or [Cu(oxpn)0.5[N(CN)2]]n [where H2oxpn is N,N'-bis(3-aminopropyl)oxamide], has been synthesized by the reaction of Cu(oxpn), [Cu(ClO4)2].6H2O and NaN3. In the crystal structure, the Cu atom is fi...