A one-step hydrothermal route is developed to prepare amino-grafted graphene oxide as an environmentally benign heterogeneous solid base catalyst.

an efficient, simple and convenient route is described for the synthesis of biscoumarin (3,3'-(arylmethylene) bis (4-hydroxy-2h-chromen-2-one)) by using of recyclable catalyst tio2@ksf. in this method, we synthesis biscoumarin derivatives via 3multi-component reactions (3mcrs) of two equivalent 4-hydroxycoumarin with one equivalent of aromatic aldehydes using 20 mg nano tio2@ksf as homogen...

A Simple and environmentally friendly  procedure for the one-pot multi-component synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives has been developed by one pot three component reaction of various aldehydes, β-dicarbonyl, and urea in the presence of catalytic amount of tris (trihexyltetradecylphosphonium) gadolinium hexachloride [P6,6,6,14]3 [GdCl6] as a solid acid catalyst without any ad...

[b(oh)3]0.78[b(oh)2(oso3h)]0.22 or (bsa) was simply prepared by addition of chlorosulfonic acid to commercial boric acid at room temperature. this cheap and green solid acid was used as an efficient catalyst for synthesis of acylals from aldehydes under solvent-free conditions at room temperature.

silica-bonded n-propyldiethylenetriamine sulfamic acid (spdtsa) is employed as a recyclable heterogeneous solid acid catalyst for the synthesis of benzopyrano[2,3-d]pyrimidines  through one-pot condensation reaction of salicylaldehydes, malononitrile and secondary amines  at room temperature under solvent-free conditions. spdtsa showed much the same efficiency when used in consecutive reaction ...

Abstract: Solid acid (heterogeneous) catalysts have a unique advantage in esterifi cation and transesterifi cation reactions which enhances the use of high acid value oil to be used as feedstock for synthesis of biodiesel. Various solid acid catalysts such as resins, tungstated and sulfated zirconia, polyaniline sulfate, heteropolyacid, metal complexes, sulfated tin oxide, zeolite, acidic ionic...

The growth of single-walled carbon nanotubes (SWCNTs) with predefined structure is of great importance for both fundamental research and their practical applications. Traditionally, SWCNTs are grown from a metal catalyst with a vapor-liquid-solid mechanism, where the catalyst is in liquid state with fluctuating structures, and it is intrinsically unfavorable for the structure control of SWCNTs....

silica-bonded n-propyldiethylenetriamine sulfamic acid (sbpdsa) was found as an efficient solid acid for the synthesis of coumarins. coumarin derivatives were obtained via the pechmann condensation reaction of phenols and β-keto-esters at 80 oc under solvent-free conditions. also, biscoumarins were obtained via the condensation of aldehydes and 4-hydroxycoumarin in water at reflux conditions. t...

The rationalisation of the influence of acidity and pore size of several solid oxides so that they selectively act as supports for preparation of encapsulated porphyrin hybrid materials or as catalysts for synthesis of porphyrins in solution is discussed. Encapsulated porphyrin yields are dependent on both the acidity and the material pore size, Al-MCM-41 being the best fitting solid, with Lewi...