Mesoporous cobalt hexacyanoferrate nanocubes (meso-CoHCF) were prepared for the first time through a facile sacrificial template method. The CoHCF mesostructures possess a high specific surface area of 548.5 m²·g-1 and a large amount of mesopores, which enable fast mass transport of electrolyte and abundant energy storage sites. When evaluated as supercapacitor materials, the meso-CoHCF materia...

Polyaniline (PANI) was successfully combined with 3DNC as supercapacitor electrodes by two commonly used method: chemical polymerization (CP) and electrochemical deposition (ECD). The combination of PANI and the 3DNC led to a fascinating result, showing high specific capacitance of 615 F/g (CP) and 1120 F/g (ECD) at the current density of 10 A/g. Both electrodes showed stable electrochemical pe...

Cobalt sulfide (Co9S8) particles are compounded as the electrode materials of supercapacitors by a mechanical alloying method. They show excellent properties including good cycling stability and high specific capacitance. A supercapacitor is assembled using Co9S8 as the anode and activated carbon (AC) as the cathode. It gains a maximum specific capacitance of 55 F ̈g ́1 at a current density of 0....

We report the synthesis of two-dimensional (2D) NiCo2O4 nanosheet-coated three-dimensional graphene network (3DGN), which is then used as an electrode for high-rate, long-cycle-life supercapacitors. Using the 3DGN and nanoporous nanosheets, an ultrahigh specific capacitance (2173 F g(-1) at 6 A g(-1)), excellent rate capability (954 F g(-1) at 200 A g(-1)) and superior long-term cycling perform...

A dual microelectrode electrochemical time-of-flight technique in which diffusion flux of Ag+, Cl-, or H+ ions electrochemically produced at a generator electrode is measured by recording potential-time transients with Ag, Ag/AgCl, or iridium oxide potentiometric microsensors, respectively, is developed. The generator and microsensor electrodes are typically spaced by 50-100 microm and are inco...

Recently, electric double layer capacitor (EDLC) with high capacitance [1] has been proposed as a sub-power source for a pure electric vehicle (PEV) or a hybrid electric vehicle (HEV) because power density of EDLC is high enough to use as the power source at start-up of the electric vehicles. However, since energy density of EDLC is quite lower than that of rechargeable batteries, the double la...

In present work, we demonstrate a simple but effective strategy for high-performance supercapacitors by adding the p-nitroaniline (PNA) into an alkaline electrolyte of KOH. PNA possesses a unique molecular structure with the functional groups of -NH2 and -NO2. Besides, both the product of nitro-reduction (-NH2) and intrinsic -NH2 on the benzene ring can lead to the occurrence of Faradaic redox ...

composite electrodes of polyaniline/mno2-multi walled carbon nanotube (pani/mno2-mwcnt), mno2-mwcnt nanocomposites and mwcnt was produced by the in situ direct coating approach. the supercapacitor performance of the nanocomposites was studied by fourier transform infrared (ft-ir) spectroscopy and scanning electron microscopy (sem). the electrochemical properties of electrodes were also investig...

This study used impedance spectroscopy measurements to extract the electrical properties of phytoplankton cells in suspension. Experimental were acquired, and single-shell model was applied specific membrane capacitance, cytoplasm permittivity, conductivity assumingly spherical suspension utilizing Maxwell’s mixture theory a controlled volume fraction cells. The suspensions algae measured at di...

A fibre-shaped solid electrochemical capacitor based on electrochemically reduced graphene oxide has been fabricated, exhibiting high specific capacitance and rate capability, long cycling life and attractive flexibility.