A bacterial strain (strain PS) was isolated from the textile effluents carrying Serilene Black BNFS® (C.I. Disp. Blk. Mix) disperse dye. The isolate was able to decolorize the dye without the need for any exogenous carbon source. Full sequencing of its 16S rRNA indicated that Bacillus sp strain PS is related to Bacillus cereus groups.  Silica- gel-thin layer chromatography of Ser...

We synthesized symmetrically insulated oligo(para-phenylene) and oligothiophene with a pseudo-linked [3]rotaxane structure by full rotation of glucopyranose units via a flipping (tumbling) mechanism in the π-conjugated guest having two permethylated β-cyclodextrin units at both ends. We also succeeded in the synthesis of an organic-soluble fixed [3]rotaxane by a cross-coupling or complexation r...

We have investigated the effect of cold drawing on the motion of phenylene rings in bisphenol-A polycarbonate by neutron scattering. The intensity scattered by isotropic and stretched polycarbonate is different, the quasielastic broadening being larger for the isotropic sample. This difference can be well accounted for by considering that preferentially oriented rings in the stretched polymer h...

Catechols were synthesized from safrole. Nine derivatives were prepared and assessed for antiproliferative effects using different human cell lines. The in vitro growth inhibition assay was based on the sulphorhodamine dye to quantify cell viability. The derivatives 4-allylbenzene-1,2-diol (3), 4 4-[3-(acetyloxy)propyl]-1,2-phenylene diacetate (6) and 4-[3-(acetyloxy)propyl]-5-nitro-1,2-phenyle...

Using variable temperature 2 H static NMR spectra and 13 C spin-lattice relaxation times (T1 ), we show that two different porous organic cages with tubular architectures are ultra-fast molecular rotors. The central para-phenylene rings that frame the "windows" to the cage voids display very rapid rotational rates of the order of 1.2-8×106  Hz at 230 K with low activation energy barriers in the...

N-alkylation reaction of amine functionalized phenylene moieties in crystal-like mesoporous silica is successfully achieved with about 87% of conversion in two reaction cycles. A potassium iodide catalyzed method commonly used for the selective N-monoalkylation of aniline is adapted and optimized to the N-monoalkylation reactions of the amine functionalized periodic mesoporous phenylene-silica ...

In this paper, new (2E, 2'E)-3, 3'-(((3- hydroxypropane-1, 2-diyl) bis (oxy)) bis (2, 1-phenylene)) bis (1-phenylprop-2-en-1-one) (2a) was prepared in good yield by condensation reaction of acetophenone with bisaldehyde (1a) in ethanolic NaOH solutions at room temperature. The (2E, 2'E)-3, 3'-(((3- hydroxypropane-1, 2-diyl) bis (oxy)) bis (2, 1-phenylene)) bis (1-phenylprop-2-en-1-one) (2a) was...

bilateral finger and palm prints of 500 males and 500 females of the caucasian origin in south iran have been collected and analyzed for both qualitative and quantitative dermatoglyhic features. results show that most of the qualitative features on bilateral and bisexual differences are not significant. however, quantitative features frequently showed significant differences both bilaterally an...

Cyclopentadienylcobalt complexes of linear [4]phenylene undergo thermally reversible photoinduced metallahaptotropism between the inner and outer cyclobutadiene ring.

Introduction: The Diels-Alder reaction of maleimide and furan groups is being exploited in self-healing materials; hence, it no wonder that with the ownership former, 1,1'-(methylenedi-4,1-phenylene) bismaleimide (BMI) counts as a potential candidate this area. However, displays certain discernible demerits arising from its inflexible structure. Furthermore, group, all likelihood, easily takes ...