This study examined the possible correlation between the degree of conversion (DC) and the amount of substances eluted from three commercial cured resin-based cements. The DC of the various resin-based cements was measured by Raman spectroscopy, while the quantity of unreacted monomers released from the cement matrix (triethylene glycol dimethacrylate, TEGDMA, urethane dimethacrylate, UDMA, 2-h...

This study examined the effects of monomer composition, original filler content, and application of centrifugal force on the resulting filler loading of composites. Either Bis-MPEPP or UDMA was mixed with TEGDMA at a molar ratio of 1 : 1. Silane-treated silica (14-20 wt%) was added to each mixture. After the mixtures were centrifuged and light-polymerized, rate of increase was determined as the...

Glucose-sensitive hydrogels were prepared by the copolymerization of diethylaminoethyl methacrylate (DEAEM), poly(ethylene glycol) monomethacrylate (PEGMA) and functionalized glucose oxidase (GOD) and catalase in solution. Tetra(ethylene glycol) dimethacrylate (TEGDMA) was used as the crosslinking agent. The equilibrium and dynamic swelling properties were studied to investigate the pHsensitive...

Introduction It is legitimate to ask questions about the harmfulness of the components released from dental biomaterials like composite resins, adhesives and pit and fissure sealants. Recent studies show that monomers and co-monomers are released in solvents like water, ethanol or methanol, especially when submitting properly polymerized restorative biomaterials to stresses simulating chewing, ...

Glass–ceramic filler particles containing various amounts of fluoroapatite–mullite crystalline phases were synthesised using SiO2–Al2O3–P2O5–CaF2–CaO system as the base glass formulation. Different additives were used to promote crystallisation in this system. Composite samples were prepared by incorporating the silane treated glass–ceramic particles into the BisGMA/TEGDMA (60 : 40 mass ratio) ...

We studied relaxation by hygroscopic expansion of the interfacial polymerization shear stress of bonded resin composites. In the experimental set-up, resin composite-cured-to-glass strips bent due to the polymerization shrinkage. The strips were stored wet or dry. The curvatures of the bent strips were recorded, by the scanning of the glass surfaces with a contact profilometer, periodically ove...

Abstract: Composite specimens were prepared by dispersion of various amounts of nano-sized Al2O3 fillers in a monomer system containing 60% Bis-GMA and 40% TEGDMA. For comparative purposes, composite samples containing micrometer size Al2O3 fillers were also prepared following the same procedure. The mechanical properties of the light- cured samples were assessed by three-point flexural strengt...