This paper presents results of the spectral (absorption and emission) and photophysical study of 6-aminocoumarin (6AC) in various aprotic hydrogen-bond forming solvents. It was established that solvent polarity as well as hydrogen-bonding ability influence solute properties. The hydrogen-bonding interactions between S1-electronic excited solute and solvent molecules were found to facilitate the...

The northwestern part of the Kerman Cenozoic magmatic arc (KCMA) contains many areas with porphyry copper mineralization. In this research, we used the advanced space-borne thermal emission and reflection radiometer (ASTER) and Enhanced Thematic Mapper plus (ETM+) images of this region to map the distribution of hydrothermally altered rocks, based on their mineral assemblages. The spectral meas...

Department of Chemistry, Faculty of Sc Yokohama, 223-8522, Japan. E-mail: hasob Department of Material and Life Science, University, ALCA, Japan Science and Tech 0871, Japan. E-mail: [email protected] Department of Applied Physics, Waseda U 169-8555, Japan. E-mail: takenobu@waseda † Electronic supplementary information MALDI-TOF mass spectra, cyclic vo uorescence titration spectra, H NMR tra...

At the present theoretical study, DFT calculations were performed for elucidating thereaction, absorption energy and the quantum molecular descriptors including electronic chemical potential, chemical hardness, Homo, Lumo, band gap energy (Eg) and finding the most active nitrogen-doped graphene sheet (N-G) for absorption H2S, CH4, N2 and CO2 gases. Finally it found that nitrogen-doped gra...

The effect of steroid substrate addition on the visible absorption and electron spin resonance (ESR) properties of cytochrome P450 was studied in bovine adrenal cortex submitochondrial particles. The interaction of ll-deoxycortisol or deoxycorticosterone produced peaks at 385, 500, and 645 nm and troughs at 420, 535, and 570 run. 2OarHydroxycholesterol produced opposite spectral effects. llDeox...

the dimerization constants of safranine t have been determined by studying the dependence of its absorption spectra on the temperature in the range 30–70 ◦c at different total concentrations of safranine t (1.03×10−5, 1.44×10−5 and 1.73×10−5 m). the monomer–dimer equilibrium of safranine t has been determined by applying mcr-als method on the absorption spectra. the quantitative analysis of the...

ABSTRACT The solvatochromic behaviour of two ketonic derivatives of benzodiazepine namely 7-chloro-1-methyl-5-phenyl-1,5-benzodiazepine-2,4-dione (Clobazam®) and 5,(2-chlorophenyl)-7-nitro-2,3-dihydro-1,4-benzodiazepine-2-one (Clonazepam®) were analysed in some selected solvents of different polarities using UV-Visible spectroscopy and DFT computational techniques. The solute-solvent interacti...

In this paper, efficient spectral modules and random number databases are developed for atomic and diatomic species for use in photon Monte Carlo (PMC) modeling of hypersonic nonequilibrium flow radiation. To model nonequilibrium flow conditions, the quasisteady state assumption was used to generate electronic state populations of atomic and diatomic gas species in the databases. For atomic spe...

the interaction between isatin-β-thiosemicarbazone (ibt) and calf thymus dna (ct-dna) was investigated in physiological buffer (ph 7.4) using neutral red (nr) dye as a spectral probe by uv–vis absorption and fluorescence spectroscopy, as well as viscosity measurements. the ibt is stabilized by intercalation in the dna ( k [ibt –dna] =1.03×105 m−1), and displaces the nr dye from the nr–dna comple...