Low-dimensional quantum magnets promote strong correlations between magnetic moments that lead to fascinating quantum phenomena. A particularly interesting system is the antiferromagnetic spin-1/2 Heisenberg chain because it is exactly solvable by the Bethe-Ansatz method. It is approximately realized in the magnetic insulator copper pyrazine dinitrate, providing a unique opportunity for a quant...

In this research, the thermodynamics and mass transfer of CO2 absorption has been studied in a mixture of MDEA-MEA amines. A relation is presented for mass transfer flux in the reactive-absorption process. For this purpose, the effective parameters on the mass transfer flux were investigated in both liquid and gas phases. Then, using dimensional analysis with the Pi-Buckingham theorem, the effe...

the complexation reaction between hydroxyl ammonium (honh3+ ) cation with 18-crown-6 (18c6) ligand was studied in dimethylsulfoxide – water (dmso-h2o), methanol – water (meoh-h2o) and dimethylformamid – methanol (dmf-meoh), binary solutions at different temperatures using conductometric method. the obtained results show that the stoichiometry of the complex formed between honh3+ cation with (18...

the basics of quantum mechanics and statistical thermodynamics were used to predict the potential energy and intermolecular forces of asphaltene molecules. the parameters associated with the chemical structure were also estimated for a specific asphaltene molecule to predict the mie potential function. based on the structural results, a new form of the virial eos with peneloux correction was de...

In this paper we propose a technique for modelling the temperature of the rooms of a smart building for control purposes. The approach consists in determining an (black-box) ARMAX model based on the first-principle thermodynamics equations of the system. Then, the model parameters are estimated by initially employing an ad hoc procedure and then by using a self-calibration method when the perfo...

We consider the thermodynamics of minimally coupled massive scalar field in 3+1 dimensional Reissner-Nordstrom de Sitter black hole background. The brick wall model of ’t Hooft is used. When Schwarzschild like coordinates are used it is found that two radial brick wall cut-off parameters are required to regularize the solution. Free energy of the scalar field is obtained through counting of sta...

First law of thermodynamics has been used to analyze and optimize inclusively the performance of a triple absorption heat transformer operating with LiBr/H2O as the working pair. A thermodynamic model was developed in EES (engineering equation solver) to estimate the performance of the system in terms of the most essential parameters. The assumed parameters are the temperature of the main compo...

The birth, raise, development and fortunes of a fundamental theory in thermodynamics, the axiomatic thermodynamics, a creation of Constantin Carathéodory, is thoroughly presented together with a summary of Carathéodory’s biography. Axiomatic thermodynamics is centered around some interesting properties of Pfaffian differential equations, which are here introduced and used for some well-known ca...

isotherm equation is one of the important scientific bases for adsorbent selection. there are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. it is interesting to introduce a general isotherm, which considers different chemisorption geometries of an adsorbate on nanoporous surfaces. in this study, an isotherm for non-dissoci...

We study the effect of impurity scattering in the unitarity limit on the A and B phase superconductivity in PrOs4Sb12. We take the triplet p+h-wave superconducting order parameters and the impurity scattering is treated within the standard theory. We find the quasiparticle density of states and thermodynamics are very sensitive to the impurity scattering. The impurity scattering dependence of t...