Pt(II) azido complexes [Pt(bpy)(N(3))(2)] (1), [Pt(phen)(N(3))(2)] (2) and trans-[Pt(N(3))(2)(py)(2)] (3) incorporating the bidentate diimine ligands 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen) or the monodentate pyridine (py) respectively, have been synthesised from their chlorido precursors and characterised by X-ray crystallography; complex 3 shows significant deviation from square-pla...

UV-visible absorption and AFM studies suggest that carboxyphenylethynyl zinc porphyrins aggregate on nanocrystalline TiO2 surfaces in an H-type fashion.

A Matlab implemented computer code for spectral resolution is presented. The code enables the user to resolve the UV-visible absorption spectrum of a mixture of up to 3 previously known components, to the individual components, thus, evaluating their quantities. The resolving procedure is based on searching the combination of the components which yields the spectrum which is the most similar (m...

The present work investigates the size dependent reflective properties of TiO2 nanoparticles and discusses the development of reflectors. The nanocrystalline TiO2 powders with different crystallinity and phase structures were obtained by controlling the reaction parameters. TiO2 nanoparticles synthesized via sol-gel method were characterized by using X-ray diffraction (XRD), transmission electr...

A rapid analysis method of piperazine ferulate tablets by optic-fiber sensing technology with UV-vis absorption spectrum was established. Qualitative and quantitative data were obtained and compared by maximum and minimum wavelength, absorbance and contrast spectra. Similarity method was used to identify authenticity of drugs. The difference of contents measured by this method and UV determinat...

Two Cd complexes have been prepared by reaction of Cd (II) with 4-(1H-Tetrazol-5yloxy) – phenylamine (HTY) and 2-(1H-Tetrazol) pyridine (HTP) ligands. These new complexes were characterized by IR, UV-Visible, 1H-NMR and 13C-NMR spectroscopies. The changes observed between the FT-IR, H-NMR and UV-Vis spectra of the ligands and complexes allowed to establish the coordination mode of the metal in ...

Tris(bipyridyl)silicon(iv) was electrochemically reduced in acetonitrile to obtain the UV-vis spectra of its reduced species. Three stable, reversible reduced states (3+, 2+, and 1+) were observed with distinct isosbestic points for each of the redox reactions. The fully oxidized state (4+) is colorless, while the reduced states were green. The absorbance spectra for the three reduced states ar...