Biogeochemical reductive dechlorination (BiRD) is a new remediation approach for chlorinated aliphatic hydrocarbons (CAHs). The approach stimulates common sulfate-reducing soil bacteria, facilitating the geochemical conversion of native iron minerals into iron sulfides. Iron sulfides have the ability to chemically reduce many common CAH compounds including PCE, TCE, DCE, similar to zero valent ...

results: the lowest concentrations of nzvi that inhibited the visible growth (mic) of e. amylovora, x. oryzae, b. cereus and streptomyces spp. were 625, 550, 1250 and 1280 ppm, respectively. the minimum bactericidal concentration (mbc) for e. amylovora and x. oryzae were 10,000 and 5,000 ppm of nzvi, respectively. mbc was not observed for the gram positive bacteria. no bacteriostatic and bacter...

The establishment of the involvement of high-valent iron-oxo intermediates in the catalytic cycles of heme and nonheme iron monooxygenases and their model compounds has been an important goal in mechanistic enzymology and bioinorganic chemistry. 2] These highly reactive and unstable intermediates are often difficult to characterize directly; therefore, O-labeled water experiments have frequentl...

Zero-valent iron has received considerable attention for its potential application in the removal of heavy metals from water. This paper considers the possibility of removal of zinc ions from water by causing precipitates to form on the surface of iron. The chemical states and the atomic concentrations of solids which have formed on the surface of zero-valent iron as well as the type of the dep...

MCM-41-supported nanoscale zero-valent iron (nZVI) was sytnhesized by impregnating the mesoporous silica martix with ferric chloride, followed by chemical reduction with NaHB4. The samples were studied with a combination of characterization techniques such as powder X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) and Mössbauer spectroscopy, N2 adsorption measurements, transmission e...

We report a metal–organic framework (MOF) with rare two-dimensional (2D) secondary building unit (SBU). The SBU comprises mixed-valent Fe2+ and Fe3+ metal ions bridged by oxygen atoms pertaining to the polytopic ligand 3,3′,4,4′,5,5′-hexahydroxybiphenyl, which also define iron-oxide 2D layers. Overall, anionic exhibits topology evidences strong electronic communication between mixed-valence iro...

Background & objectives: In recent years, iron nanoparticles have been successfully used to remove water pollutants. Fecal coliform is one of the parameters that reduces water quality and its removal is essential. The aim of the present study is using nanoscale zerovalent iron particles to enhance the usual sand filters in removal of fecal coliform of groundwater in Ilam city. Methods: Water s...

Recently, iron nanoparticles are increasingly being tested as adsorbents for various types of organic and inorganic pollutants. In this study, nanoparticles of zero-valent iron (NZVI) synthesized under atmospheric conditions were employed for the removal of Ba(2+) ions in a concentration range 10(-3) to 10(-6) M. Throughout the study, (133)Ba was used as a tracer to study the effects of time, c...