The oxidation of o-xylene to phthalic anhydride is one of the important industrial processes based on selective oxidation reactions. For the last 50 years vanadia titania catalysts have been used in this process. The reaction parameters like temperature range of operation, reactor inlet pressure, contact time, etc. slightly changed during this continuous process optimization. However, the funda...

To understand the structure-reactivity relationships for mixed-metal oxide catalysts, well-defined systems are required. Mixtures of vanadia and titania (TiO2) are of particular interest for application in heterogeneous catalysis, with TiO2 often acting as the support. By utilizing high-resolution scanning tunneling microscopy, we studied the interaction of vanadium (V) with the anatase TiO2(10...

The loss of permeability affects the reduction ferrous burden in cohesive zone a blast furnace (BF). Vanadia–titania magnetite (VTM) various chemical compositions have different metallurgical properties. and softening-melting-dripping properties kinds VTM were investigated. results showed that core sinter or pellet is indirectly reduced to wustite (Fe,Ti)Ox, periphery contains interlinked metal...

We designed a ceria-vanadia/silica (Ce-V/SiO2) heterogeneous catalyst and used it for the green and efficient synthesis of 2-amino-3-cyano-4H-pyran derivatives. The green reaction was a multicomponent one-pot condensation of 5,5-dimethylcyclohexane-1,3-dione, aromatic aldehyde, and malononitrile in an eco-compatible solvent (ethanol). The catalyst was synthesized and fully characterized by powd...

TiO2 supports doped with different amounts of Si were prepared by a sol-gel method, and 1 wt% vanadia (V2O5) loaded on Si-doped TiO2 was obtained by an impregnation method. The mole ratio of Si/Ti was 0.2, NOx conversion exceeds 94% at 300 degrees C and GHSV of 41,324 hr(-1), which is about 20% higher than pure V2O5/TiO2. The catalysts were characterized by XRD, BET, TEM, FT-IR, NH3-TPD, XPS, H...