This work presents a comparative study of the analytical characteristics of two methods for the analysis of carbonyl compounds in wine, both based on the derivatization with O-(2,3,4,5,6-pentafluorobenzyl)hydroxylamine hydrochloride (PFBHA). In the first method derivatives are formed in the solid phase extraction (SPE) cartridge in which the analytes have been previously isolated, while in the ...

A facile and highly efficient method have been developed for the preconcentration of the mercury content in crude oil and gasoline samples after digestion with microwave-assisted digestion. Octadecyl silica membrane disk has been modified by the recently synthesized triazene ligand, (E)-1-(2-ethoxyphenyl)-3-(4-nitrophenyl) triaz-1-ene (ENT), then the modified membrane was used for the preco...

exposure to mercury (hg) as a heavy metal can cause health effects. the objective of this study was to assess occupational exposure to hg in a chlor-alkali petrochemical industry in iran by determining of hg concentrations in air, blood and urine samples.the study was performed on 50 exposed subjects and 50 unexposed controls. air samples were collected in the breathing zone of exposed subjects...

The primary objective of this paper is to enhance the water-vapor-adsorption capacity of multiwall-carbon-nanotube (MWCNT) from nitrogen gas by grafting sulfonic acid groups and doping palladium nanoparticles into the adsorbent. MWCNT has been selected to be modified because of having homogeneous adsorption energy compared to silica gel. As a result, it is capable of creating isotherm having sh...

prediction of available vapor pressure data in the case of compounds containing c-h-o led to derivations and recommendations of standard equations for this property. the accuracy of vapor pressure estimations is essential to use as a basis to calculate acentric factor, thermal and equilibrium properties. in this study, according to the previous work, an accurate equation to estimate vapor press...