Water gas shift reactions (WGS) were evaluated over Ni/CeO2 and Ni/CeSmO catalysts for hydrogen production. The effects of catalyst preparation method Sm loading investigated. Ni/ceria synthesized by combustion, sol gel gel-combustion method. After WGS tests, the determined carbon deposition thermogravimetric analysis. analysis temperature programmed NH3 desorption showed that addition promoter...

Silicon microreactors with thin-film wall catalyst were adopted for kinetic studies of CO preferential oxidation (PrOx). The activity of this catalyst was compared to other catalyst systems based on similar formulation. Internal and external mass transport and heat transport limitations of the microreactor were examined and comparisons were made to typical packed-bed lab reactors (m-PBR's). We ...

Hydrogen based proton exchange membranes (PEM) fuel cells show good potential for production of electricity. However, widespread commercialization of PEM fuel cells will depend on cheap and environmentally benign production of hydrogen. Currently, hydrogen is mainly produced from syngas by the water-gas shift (WGS) reaction (CO+H2O↔CO2+H2) followed by preferential oxidation (PROX) of CO. Extens...

Context The CO2CRC is involved in research, development and demonstration of a number of different methods for the large scale capture of carbon dioxide. The Engineering Development Group within the CO2CRC is involved with assessing and optimization the process designs associated with the capture of CO2. The Engineering Development Group recently assessed a number of capture methods for air blo...

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...

Typing of group A Streptococcus (GAS) is crucial for infection control and epidemiology. While whole-genome sequencing (WGS) is revolutionizing the way that bacterial organisms are typed, it is necessary to provide backward compatibility with currently used typing schemas to facilitate comparisons and understanding of epidemiological trends. Here, we sequenced the genomes of 191 GAS isolates re...

2.1 Background .................................................................................................... 26 2.2 Syngas Classification Based on its Heating Value ........................................ 28 2.2.1 Low-Btu Gas ...................................................................................... 29 2.2.2 Medium-Btu Gas........................................................

In this research, Fischer Tropsch synthesis (FTS) has been modeled in the fixed bed chromatographic reactor for the first time by applying a rather complex dispersed plug flow model for fluid phase and linear driving force (LDF) model for adsorbent. Model equations are dynamic, multi-component, non-linear and heterogeneous including reaction and adsorption simultaneously Complex kinetics fo...

Approach • Complete reverse kinetics and Computational Fluid Dynamics (CFD) modeling to optimize reactor geometry for forward reactions • Measure forward kinetics in quartz & Inconel reactors to determine reactor wall catalysis • Measure forward kinetics in reactor packed with membrane material to determine catalytic activity • Measure membrane H2 permeability in presence of clean syngas compon...