The reactions of hydrogen with the 14-electron high-spin iron( 1 1 ) dialkyls of stoichiometry [ FeRJdippe)] [dippe = 1,2-bis(diisopropylphosphino)ethane] have been studied. The p-methylbenzyl complex in diethyl ether yielded the zerovalent p-xylene complex [Fe(q6-C,H4Me,-1 ,4) (dippe)], where the arene ligand has been formed by addition of a hydrogen atom to the a-carbon of the p-methylbenzyl ...

Abstract In recent times, nano zerovalent iron (nZVI) particles have attracted significant attention from researchers for their effectiveness in removing phosphates, a hazardous contaminant found groundwater and surface water. nZVI possesses some excellent characteristics such as high reactivity, area, effective surface-to-volume ratio. this study, was characterized by X-ray diffraction, Brunau...