نتایج جستجو برای: نانوکاتالیست Ni-Cu/Al2O3-ZrO2
تعداد نتایج: 55828 فیلتر نتایج به سال:
در این مطالعه تأثیر روش سنتز سل-ژل در مقایسه با روش پرکاربرد تلقیح بر خواص و عملکرد کاتالیست ni-cu/al2o3-zro2 در فرآیند ریفورمینگ خشک متان مورد ارزیابی قرار گرفت. خواص کاتالیست ها توسط آنالیزهای xrd ، fesem، اpsd،ا betا، edsا، ftir و tg-dtg بررسی گردیدند. نتایج آنها نشان داد روش سل-ژل در مقایسه با روش تلقیح سبب افزایش یکنواختی اندازه ذرات شده، اما به دلیل فشردگی ذرات و کاهش فضاهای متخلخل، سطح و...
کار حاضر بر تولید هیدروژن از طریق فرآیند خودگرمایی اتانول (atr)، در حضور نانوکاتالیست zro2/γ-al2o3 متمرکز شده است. نانوذرات زیرکونیوم اکسید با روش مایسل معکوس و با استفاده از zrocl2·8h2o و nh4oh تهیه شد. نانوکاتالیست های zro2/γ-al2o3 با توزیع پایدار نانوذرات zro2 بر پایه ی گاما آلومینا به روش مکانیکی تهیه شدند. اثر اندازه ذرات با تغییر نسبت مولی zr:al مطالعه شد. نانوکاتالیست ها با استفاده از می...
A novel hydrothermal zirconium oxide (ZrO2) ion exchange material was successfully synthesized by hydrothermal technique. The material has been characterized using different tools such as thermal analysis (DTA-TGA), FT-IR and X-ray diffraction studies. The results show that the prepared ZrO2 is pure and with a unique shape and it belongs to the hexagonal system. Chemical resistively of the mate...
Ni nanoparticles supported on ZrO2 are a prototypical system for reforming catalysis converting methane to synthesis gas. Herein, we examine this catalyst on a fundamental level using a 2-fold approach employing industrial-grade catalysts as well as surface science based model catalysts. In both cases we examine the atomic (HRTEM/XRD/LEED) and electronic (XPS) structure, as well as the adsorpti...
First principles( or ab initio) density-functional-theory (DFT) with projected augmented wave (PAW) method simulations were performed to calculate the electronic structures and optical properties of 25% nickel (Ni) doped cubic ZrO2 crystals. We implemented two ab initio DFT application methods to the ZrO2 ceramic elastic constant, structure stability, and optical property calculation. The Cerpl...
Nucleation and growth of transition metals on zirconia has been studied by scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. Since STM requires electrical conductivity, ultrathin ZrO2 films grown by oxidation of Pt3Zr(0001) and Pd3Zr(0001) were used as model systems. DFT studies were performed for single metal adatoms on supported ZrO2 films as well as the (1̅...
We have studied the ZrO2~111!/Ni~111! interface using the ultrasoft pseudopotential formalism within density functional theory. We find that ZrO2(111) adheres relatively strongly at the monolayer level but thicker ceramic films interact weakly with the Ni-substrate. We argue that the cohesion changes character from dominantly image charge interactions for thick ceramic films to more covalent fo...
Citation: Charisiou ND, Siakavelas G, Papageridis KN, Baklavaridis A, Tzounis L, Goula G, Yentekakis IV, Polychronopoulou K and Goula MA (2017) The Effect of WO3 Modification of ZrO2 Support on the Ni-Catalyzed Dry Reforming of Biogas Reaction for Syngas Production. Front. Environ. Sci. 5:66. doi: 10.3389/fenvs.2017.00066 The Effect of WO3 Modification of ZrO2 Support on the Ni-Catalyzed Dry Re...
Nano-sized, nonreacting, noncoarsening ZrO2 particles reinforced Sn–3.0 wt%Ag–0.5 wt%Cu composite solders were prepared by mechanically dispersing ZrO2 nano-particles into Sn–Ag–Cu solder. The interfacial morphology of unreinforced Sn–Ag–Cu solder and solder joints containing ZrO2 nano-particles with Au/Ni metallized Cu pads on ball grid array (BGA) substrates and the distribution of reinforcin...
Ni–CeO2–ZrO2 Catalysts for Water Gas Shift Reaction: Effect of CeO2
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