A reaction model was developed for the pyrolysis of binary mixtures of compounds whose reactions can be apportioned into three or fewer parallel chains coupled by chain transfer. A representative application of this model to the pyrolysis of mixtures of the asphaltene model compounds n-pentadecylbenzene (PDB) and n-tridecylcyclohexane (TDC) illustrates its utility. The model, along with its ass...

The thermogravimetric characteristics of wheat straw EMAL (Enzymatic Acidolysis Lignin) were analyzed. The effect of the heating rates on the thermogravimetric characteristics of wheat straw and the wheat straw influence on pyrolysis were investigated. The influence of various heating rates on wheat straw was significant, the pyrolysis rate of wheat straw EMAL increased at temperatures between ...

FATE OF MICROPOLLUTANTS DURING PYROLYSIS OF BIOSOLIDS Approximately 250 tons of organic micropollutants, including pharmaceuticals, antimicrobials, and hormones, are discharged to the environment during land application of wastewater biosolids. Reusing wastewater biosolids is vital to the sustainability of wastewater treatment, but current treatment processes do not remove micropollutants from ...

The new compounds [H2GaE(SiMe3)2]3 (E ) P (1), As (2)), the first authenticated examples of a phosphinogallane and an arsinogallane containing the GaH2 moiety, are prepared Via efficient dehydrosilylation from the respective combinations of H3Ga‚NMe3 and E(SiMe3)3 in diethyl ether or toluene. Compounds 1 and 2 are characterized by elemental analysis, NMR, IR, and mass spectrometry. Single-cryst...

the paper introducedeffects of modified pyrolysis tar on flue gas desulfurization. this experiment selected the pyrolysis tar as the raw material, researched the effects on desulfurization performance under different modification solution, concentration, solid liquid ratio of pyrolysis tar and modified solution, calcination temperature and calcination time by 16 group orthogonal experiments. th...

This paper describes the aging behavior of the oil impregnated repulped cellulose and compares it with the aging behavior of the oil impregnated standard cellulose. In order to evaluate the reliability of using repulped cellulose in transformers, the accelerated aging process was applied to both types of cellulose by increasing the temperature to 150 °C and their aging behavior was studied and ...

This paper aims to provide a review of the analytical extraction techniques for polycyclic aromatic hydrocarbons (PAHs) in soils. The extraction technologies described here include Soxhlet extraction, ultrasonic and mechanical agitation, accelerated solvent extraction, supercritical and subcritical fluid extraction, microwave-assisted extraction, solid phase extraction and microextraction, ther...

Biomass was subjected to conventional and microwave pyrolysis, to determine the influence of each process on the yield and composition of the derived gas, oil and char products. The influence of pyrolysis temperature and heating rate for the conventional pyrolysis and the microwave power was investigated. Two major stages of gas release were observed during biomass pyrolysis, the first being CO...

the purposes of this article are studying the effects of oxygen presence on waste wood pyrolysis process in order to produce bio-char. to reach the goal, cubic samples of size 2.5 cm pyrolized at 300 and 400 °c. the surface and center temperatures of samples were measured and their mass losses were calculated from the ratio of pyrolized mass to initial mass of the sample. increase in temperatur...

The co-pyrolysis of waste electrical and electronic equipments (WEEEs) and waste biomass to obtain pyrolysis-oil, a liquid fuel or chemical feedstock, was carried out in the present work. The pyrolysis-oil yield of co-pyrolysis reached 62.3% which was significantly higher than those of pyrolysis of WEEEs and biomass alone (i.e., 53.1% for WEEEs and 46.3% for biomass), suggesting that synergisti...