نتایج جستجو برای: Acetyl acetone

تعداد نتایج: 35557  

2011
Qing-Fu Zhang Jian-Dong Pang De-Zhi Sun Cai-Hua Liu

In the title compound, C(10)H(11)NO(2)S, the acetyl-acetone group crystallizes in the keto form with all the non-hydrogen atoms in the acetyl-acetone group approximately co-planar with a maximum atomic deviation 0.055 (2) Å; the dihedral angle between the acetyl-acetone group and the pyridine ring is 85.90 (6)°. An intra-molecular O-H⋯O hydrogen bond involving the acetyl-acetone group forms a s...

Journal: :iranian journal of pharmaceutical sciences 0
nurmaya effendi department of chemical pharmacy, moslem university of indonesia, indonesia kosman rachmat department of chemical pharmacy, moslem university of indonesia, indonesia passuke akbar department of chemical pharmacy, moslem university of indonesia, indonesia naid tadjuddin department of chemical pharmacy, hasanuddin university, indonesia

gabapentin is an anticonvulsant widely used in the treatment of epilepsy.an accurate and validated spectrophotometric method was developed as an alternative method to determine gabapentin in pharmaceutical products. this is a simple, accurate, precise, selective and visible spectrophotometric method. the method is based on the measurement of drug absorbance as a result of yellow solution format...

Journal: :Journal of bacteriology 1995
P H Janssen B Schnik

Acetone degradation by cell suspensions of Desulfococcus biacutus was CO2 dependent, indicating initiation by a carboxylation reaction, while degradation of 3-hydroxybutyrate was not CO2 dependent. Growth on 3-hydroxybutyrate resulted in acetate accumulation in the medium at a ratio of 1 mol of acetate per mol of substrate degraded. In acetone-grown cultures no coenzyme A (CoA) transferase or C...

In this study, TiO2-10%wt. carbon nanotube (CNT) nanocomposite powders were synthesized by sol-gel method at various hydrolysis rate affected by different reaction agents of acetyl acetone and benzyl alcohol. Crystallization of TiO2 was then achieved through calcination at 400 °C. The properties of nanocomposite powder investigated by scanning electron microscopy, X-ray diffraction and diffuse ...

Journal: :FEMS microbiology letters 2015
Margreet J Oosterkamp Sjef Boeren Siavash Atashgahi Caroline M Plugge Peter J Schaap Alfons J M Stams

Alicycliphilus denitrificans strain BC grows anaerobically on acetone with nitrate as electron acceptor. Comparative proteomics of cultures of A. denitrificans strain BC grown on either acetone or acetate with nitrate was performed to study the enzymes involved in the acetone degradation pathway. In the proposed acetone degradation pathway, an acetone carboxylase converts acetone to acetoacetat...

Journal: :Biotechnology and bioengineering 2009
Ryan Sillers Mohab Ali Al-Hinai Eleftherios T Papoutsakis

Metabolic engineering (ME) of Clostridium acetobutylicum has led to increased solvent (butanol, acetone, and ethanol) production and solvent tolerance, thus demonstrating that further efforts have the potential to create strains of industrial importance. With recently developed ME tools, it is now possible to combine genetic modifications and thus implement more advanced ME strategies. We have ...

2016
Jun-Won Chwa Wook Jin Kim Sang Jun Sim Youngsoon Um Han Min Woo

Capture and conversion of CO2 to valuable chemicals is intended to answer global challenges on environmental issues, climate change and energy security. Engineered cyanobacteria have been enabled to produce industry-relevant chemicals from CO2 . However, the final products from cyanobacteria have often been mixed with fermented metabolites during dark fermentation. In this study, our engineerin...

Journal: :Physical chemistry chemical physics : PCCP 2016
Krisztina Voronova Chrissa M Mozaffari Easter Krisztián G Torma Andras Bodi Patrick Hemberger Bálint Sztáray

The fragmentation processes of internal energy selected acetic acid anhydride cations, Ac2O+, were investigated by imaging photoelectron photoion coincidence (iPEPICO) spectroscopy. The first dissociation channel leads to the formation of CH3C(O)OCO+ (m/z = 87) by a CH3-loss. The 0 K appearance energy (E0) was determined to be 10.289 ± 0.010 eV, in excellent agreement with the G4-calculated 10....

2012
Rik Van Deun Pascal Van Der Voort Isabel Van Driessche Kristof Van Hecke

The title compound, (C(8)H(20)N)[Tb(C(5)HF(6)O(2))(4)], is a tetrakis β-diketonate complex of hexa-fluoro-acetyl-acetone with terbium(III), and tetra-ethyl-ammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the Tb(III) atom is a slightly distorted square anti-prism. One hexa-fluoro-acetyl-ace...

2008
Uzma Yunus Muhammad Kalim Tahir Moazzam Hussain Bhatti Wai-Yeung Wong

The title compound, C(5)H(6)N(2)OS, was synthesized from acetyl chloride and 2-amino-thia-zole in dry acetone. The asymmetric unit contains two mol-ecules. The crystal structure is stabilized by N-H⋯N and C-H⋯O hydrogen bonds.

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