Thermodynamic predicting analysis of three binary systems Al-Fe, Al-Ni and Ni-Fe are shown in this paper. Thermodynamic analysis involved calculation of activities, coefficient of activities, partial and integral values for enthalpies and Gibbs energies of mixing and excess energies at three different temperatures: 1873K, 1900K and 1973K, as well as calculated phase diagrams, for the investigat...

The preparation and spectroscopic characterization of a CO-inhibited [FeFe] hydrogenase with a selectively (57)Fe-labeled binuclear subsite is described. The precursor [(57)Fe2(adt)(CN)2(CO)4](2-) was synthesized from the (57)Fe metal, S8, CO, (NEt4)CN, NH4Cl, and CH2O. (Et4N)2[(57)Fe2(adt)(CN)2(CO)4] was then used for the maturation of the [FeFe] hydrogenase HydA1 from Chlamydomonas reinhardti...

A mathematical model was developed which evaluates the effect of the applied deposition parameters on the composition of deposited Fe-Ni-Si02 composites. This model assumes that the discharge rates of Fe(OH)+ and Ni(OH)+ are proportional to their respective surface coverage fraction. The inclusion of Si02 with the deposited alloys is considered. Introduction Fe-Ni deposition is classified as an...

The densification behavior, microstructure and mechanical properties of bulk TiB₂-based ceramic composites, fabricated using the spark plasma sintering (SPS) technique with elements of (Fe-Ni-Ti-Al) sinter-aid were investigated. Comparing the change of shrinkage displacement of pure TiB₂ and TiB₂-5 wt% (Fe-Ni-Ti-Al), the addition of elements Fe-Ni-Ti-Al into TiB₂ can facilitate sintering of the...

Long-lived goal reasoning systems that reason over their history confront the bounding problem–the impracticality of reasoning over a large, ever-growing experience-base. This is a problem with some explanation systems that use the history of their observations to inform beliefs about the current state of the world. We propose to apply narrative intelligence (NI), which includes the ability to ...

This paper intends to review the state-of-the-art in the field of ferromagnetic shape memory alloys different than Ni–Mn–Ga, developed in the ast years. It starts with the effects of additions of different fourth elements to Ni–Mn–Ga and continues with the review of other Heusler (or B2) i-based and Co-based alloy systems, like Ni–Mn–X, Ni–Fe–Ga, Co–Ni–Al and Co–Ni–Ga alloys. Finally, ferromagn...

This paper describes a study of excited-state properties of naphthalimide (NI) and four 4-substituted derivatives: 4-chloronaphthalimide (Cl-NI), 4-methylthionaphthalimide (MeS-NI), 4-nitronaphthalimide (O(2)N-NI), and 4-(N,N-dimethylaminonaphthalimide (Me(2)N-NI). Steady-state absorption and fluorescence spectra were collected in solvents of varying polarity to determine the excited-state char...

Five Ni-Cr alloys were studied in order to identify the compounds formed on the alloy surface during oxidation under conditions similar to those encountered during dental laboratory procedures prior to application ofporcelain. After the alloys were oxidized, the films covering the surfaces were removed with the aid of a Br-methanol solution. X-ray diffraction was used to analyze the compounds f...

BACKGROUND The present work was designed to detect heavy metal contents of Al, Zn, Fe, Mn, Ni, V, Co, Cr and Cu in sediments and shells of the Trachycardium lacunosum collected in polluted and unpolluted areas along the Persian Gulf. METHODS The samples were taken from surface sediments (0-10 cm) and shells of Trachycardium lacunosum in two separated areas (polluted and unpolluted) in norther...