1. An artificial facilitated amino-acid-transfer process operating across a chloroform phase is reported. 2. This process utilizes a family of bis(salicylamidato)copper(II) complexes. 3. A mechanism is proposed for this process and for its sensitivity towards cyanide and bathophenanthroline sulphonate. 4. Facilitated transfer of L-leucine in human erythrocytes has been shown to be inhibited by ...

We have demonstrated directional photoinduced electron transfer in paraquat silicate thin films containing entrapped ruthenium(II)-tris(bathophenanthroline-disulfonate (RuBPS). The films were made by electrochemically-induced hydrolysis of a silane analogue of paraquat with ruthenium(II)-tris(bathophenanthroline-disulfonate as its ion pair.

The asymmetric unit of the title compound, C24H16N2·0.5CH3OH, is comprised of two independent bathophenanthroline mol-ecules (systematic name: 4,7-diphenyl-1,10-phenanthroline) and one methanol mol-ecule. The bathophenanthroline mol-ecules are not planar as there is a considerable rotation of all terminal phenyl rings with respect to the central phenanthroline units [dihedral angles in the rang...

A comparison between two fluorescent metal chelates for staining proteins separated by electrophoresis has been carried out. One of these chelates is ruthenium II tris (bathophenanthroline disulfonate) and the other is commercial Sypro Ruby. Both can be efficiently detected either with UV tables or with commercial laser fluorescence scanners. The sensitivity and homogeneity of the stains and th...

An improved microprocedure for the determination of tocopherol in blood serum is reported. Tocopherol is oxidized by ferric chloride and the pink complex of ferrous ions with 4,7-diphenyl10,10-phenanthroline (bathophenanthroline) is determined spectrophotometrically. The test is more sensitive than colorimetric methods using 2,2’,2” -tripyridine,2,2’-bipyridine (bipyridyl) or 2,4,6tripyridyl-s-...

Two new organo-europium complexes (OEuCs) [Eu(btfa)3(Bathphen)] (OEuC-1) and [Eu(tta)3(Bathphen)] (OEuC-2) where btfa tta are the anion of 4,4,4-trifluoro-1-phenyl-1,3-butanedione 2-thenoyltrifluoroacetonehave while Bathphen = Bathophenanthroline been synthesized characterized. Both...

Improved methods are described for the determination of serum iron (SeFe) and latent iron-binding capacity under controlled conditions of pH. As before, no precipitation or heating of the serum is required, and controls are not used. Unbuffered sulphonated bathophenanthroline is employed for colour development. Statistical data for 40 normals are presented and comparisons with other data are gi...

a new sensitive and selective spectrophotometric method for the determination of iron using a pvc membrane containing bathophenanthroline and dioctylphethalate as the solid phase extraction medium is investigated. fe(ii) in an aqueous sample solution is trapped on the membrane with an anion species, picrate ion and forms a complex with bathophenanthroline. the absorbance of the red-orange membr...

Passing–Bablok analysis showed that results obtained with the two chromogens were correlated. The Bland– Altman difference plot (Fig. 1) showed that eight of the paired values were outside of the 95% confidence interval (Ϫ2.6 and 4.2). These values fell nearly within the limits of agreement, and medical acceptance remained possible. The determination of low HIC with ferene gave better sensitivi...

Erbium complexes featuring β-diketonate ligand 2,4-hexanedione (Hh) and N,N-donor-ligands 2,2'-bipyridine (bipy), 5-nitro-1,10-phenanthroline (5NO2phen) and bathophenanthroline (bath) have been synthesized. The structures of the ternary complexes [Er(h)3(bipy)], [Er(h)3(5NO2phen)] and [Er(h)3(bath)] have been determined by single crystal X-ray diffraction. Excitation of the complexes in the ult...