boron carbide is one of the hardest materials. the combustion method was used to synthesize b4c-tib2 nanocomposite powder in a b2o3-mg-tio2-c system. an experimental study of the formation of b4c–tib2 nanoparticles was conducted in the thermal explosion mode. a mixture of b2o3:tio2:mg:c at a molecular ratio of 3:1:12:1 was chosen to obtain the b4c–tib2. this powder mixture was milled for differ...

Our present work presents a direct association of the observed loss of shear strength in boron carbide under plane shock wave compression to amorphization in boron carbide under triaxial stress compression. This evidence is obtained from in-situ measurement of Raman, and infrared vibrational spectra of boron carbide confined in a Diamond Anvil Cell (DAC) under hydrostatic and non-hydrostatic pr...

In this paper, new various morphologies of boron carbide were successfully synthesized using carbon black, activated carbon and boron oxide precursors as well as using cobalt nanoparticles as catalysts. Almost the whole morphology of synthesized boron carbide are consisted of smooth nanowires and nanobelts. With decreasing the carbon black particles size from 29 nm to 13 nm (29, 23, 17 and 13),...

A unique combination of useful properties in boron-carbide, such as extreme hardness, excellent fracture toughness, a low density, a high melting point, thermoelectricity, semi-conducting behavior, catalytic activity and a remarkably good chemical stability, makes it an ideal material for a wide range of technological applications. Explaining these properties in terms of chemical bonding has re...

A boron carbide coating was applied to diamond particles by heating the particles in a powder mixture consisting of H3BO3, B and Mg. The composition, bond state and coverage fraction of the boron carbide coating on the diamond particles were investigated. The boron carbide coating prefers to grow on the diamond (100) surface than on the diamond (111) surface. A stoichiometric B4C coating comple...

This paper describes the fabrication and mechanical testing of Al-Mg-boron carbide particulate composites using stir casting technique. The size of the boron carbide particulates is ranging between 30 to 100 μm. The boron carbide contents are varied from 3 and 7% by weight and are dispersed in the alloy matrix. The mechanical properties of the castings, particularly their tensile properties and...

Boron carbide is one of the lightest and hardest ceramics, but its applications are limited by its poor stability against a partial phase separation into separate boron and carbon. Phase separation is observed under high non-hydrostatic stress (both static and dynamic), resulting in amorphization. The phase separation is thought to occur in just one of the many naturally occurring polytypes in ...

In this study, Boron carbide was synthesized using Mesoporous Carbon CMK-1, Boron oxide, and magnesiothermic reduction process. The Effects of temperature and magnesium grain size on the formation of boron carbide were studied using nano composite precurser containg mesoporous carbon. Samples were leached in 2M Hydrochloric acid to separate Mg, MgO and magnesium-borat phases. SEM, XRD and Xray ...

Titanium diboride is one of the candidate materials for high temperature applications and also for control rod elements in high temperature reactors. This paper presents the experimental data on the composites of B4 C-nano TiB2 that were synthesized successfully by co-precipitation methodat 1523K. Titanium tetraisopropanol, boron carbide, isopropanol and triton x-100were used as the precursor m...

Findings of laser-assisted atom probe tomography experiments on boron carbide elucidate an approach for characterizing the atomic structure and interatomic bonding of molecules associated with extraordinary structural stability. The discovery of crystallographic planes in these boron carbide datasets substantiates that crystallinity is maintained to the point of field evaporation, and character...