This study aimed to examine the effect of CO2 atmosphere during pyrolysis of solid fuel on the gasification of its char by using thermobalance. As the sample, alkali-rich lignin was prepared. The lignin sample was pyrolyzed at heating rate of 1K/s to 700C under CO2 and Ar, and these chars (ligninchar-CO2, ligninchar-Ar) are gasified in air at various temperatures, from 700C to 1140C. The differ...

Coal gasification with carbon dioxide is a process for generating clean gaseous fuels and relieving greenhouse effect. Zhundong coal has high alkali and alkali earth metals (AAEMs) content, medium volatile and low ash in nature. Isothermal CO2 gasification of char derived from Zhundong coal (R-char) and char from acid washing R-char (AR-char) are performed in thermo-gravimetric analyzer (TGA). ...

In this paper, measurements of the CO2 gasification kinetics for two types of Shenfu coal chars, which were respectively prepared by slow and rapid pyrolysis at temperatures of 950 °C and 1,400 °C, were performed by an isothermal thermo-gravimetric analysis under ambient pressure and elevated temperature conditions. Simultaneously, the applicability of the kinetic model for the CO2 gasification...

In the current study a series of pyrolysis and CO2 gasification experiments were conducted on a bed of kraft black char under a perpendicular impinging jet. The experiments demonstrated that the char bed carbon gasification rates are externally mass transfer limited. The mass transfer is further decreased by a net molar out-flow caused by the conversion of one mole of reactant CO2 to two moles ...

Carbonaceous adsorbents with controllable surface area and the microporous volume ratio (Vmicro/Vpore) were activated from carbonized corncobs (i.e., char) with KOH etching plus CO2 gasification in this work. Activated carbons derived from KOH/char ratio equal to 1 and CO2 gasification time from 0 to 60 min exhibited BET surface area increasing from 1071 to 1991 m2 g−1 and the Vmicro/Vpore valu...

In this work, char gasification of two coals (i.e., Shenfu bituminous coal and Zunyi anthracite) and a petroleum coke under a steam and CO2 mixture (steam/CO2 partial pressures, 0.025–0.075 MPa; total pressures, 0.100 MPa) and CO2/steam chemisorption of char samples were conducted in a Thermogravimetric Analyzer (TGA). Two conventional kinetic models exhibited difficulties in exactly fitting th...

Biomass and coal gasification is a rapidly developing technology due to the increasing global demand for fossil fuel resources. Gasification is the process of conversion of solid carbonaceous feedstock to a gas mixture containing CO and H2 in the presence of steam or carbon dioxide. Past research on coal gasification has shown that the process requires high temperatures (> 800 oC) and produces ...

Recovery of energy from MSW by combustion in Waste-to-Energy (WTE) plants reduces land filling and air/water emissions, and also lessens dependence on fossil fuels for power generation. The objective of this study was to assess the potential of gasification processes as an alternative to the combustion of MSW. Gasification uses a relatively small amount of oxygen or water vapor to convert the o...

Gasification technology has been investigated to effectively and economically convert lowvalue and highly distributed solid biomass to a uniform gaseous mixture mainly including hydrogen (H2), carbon monoxide (CO), methane (CH4) and carbon dioxide (CO2). This gaseous mixture can be further used as an industrial feedstock for heat and power generation, H2 production and synthesis of liquid fuels...

Coal is a prime energy source in India and will continue to play its role for coming several decades. However, our indigenous coal suffers from high ash content and present coal based conventional power generation technologies have several drawbacks such as, lower efficiency, environmental loading and damages thereof. Herein the importance of gasification lies because coal gasification is a mea...