the ultraviolet-visible (uv) spectra of toluene, ortho-bromo and para-bromo toluene in different solvents have been studied. the electric dipole moments and polarizabilities in the molecular excited electronic states were determined. it was found that the electric dipole moments for the excited states (µ*) and the ground states (µ) of these compounds are equal, and the change in dipole moment i...

The Ultraviolet-visible (UV) spectra of toluene, ortho-bromo and para-bromo toluene in different solvents have been studied. The electric dipole moments and polarizabilities in the molecular excited electronic states were determined. It was found that the electric dipole moments for the excited states (µ*) and the ground states (µ) of these compounds are equal, and the change in dipole moment i...

VI. REACTION MoMErcr AND ELECTRIc-CI~-.MICAL MECHANISM 1. Reaction Moments from Dielectric Data 2. Permanent and Induced Dipole Moments (a) Individual dipole moments (b) Total polarization (i) Induced moment (ii) Permanent moment (c) Form factors and g-factors 3. Reaction Moment and Equilibrium Constant (a) Non-polar polarizable spheres (b) Polar non-polarizable spheres (c) Polar polarizable sp...

We review some of the few available nonadiabatic calculations of dipole moments. We show that those carried out in a laboratory–fixed set of coordinate axes are bound to fail and discuss the more reasonable ones in a molecule–fixed reference frame. For completeness we also describe the standard Born–Oppenheimer calculations of dipole moments. We briefly address the experimental estimation of di...

The effect of core polarization on isoscalar dipole one-particle moments due to the coupling with isoscalar giant dipole resonance ~compression mode! is estimated. Numerical calculations with the core nucleus 82 Pb126 show that a small enhancement of one-particle moments is obtained, of which the magnitude depends sensitively on relevant one-particle orbitals. The results are important for a mi...

Dipole and higher moments are physical quantities used to describe a charge distribution. In analogy with electromagnetism, it is possible to define the dipole moments for a gray-scale image, according to the single aspect of a graytone map. In this paper we define the color dipole moments for color images. For color maps in fact, we have three aspects, the three primary colors, to consider. As...

The ground state (μg) and excited state (μe) dipole moments of two coumarin derivatives namely diethyl 2acetamido-2-((3-oxo-3H-benzo[f]chromen-1-yl)methyl)malonate (2DAM) and ethyl2-((7-methyl-2-oxo-2H-chromen-4yl)methyl)-3-oxobutanoate(2EMCO) were estimated in various solvents. The dipole moments were estimated from Lippert, Bakhshiev and Kawaski-Chamma-Viallet equations by using the variation...