in the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. the effect of tio2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. membrane wate...

in this research, polyvinylchloride based composite heterogeneous cation exchange membranes were prepared by the solution casting technique. chitosan-co-iron nickel oxide nanoparticles were utilized as membrane surface modifier to improve the membranes electrochemical properties. the effect of additive nanoparticle concentration in the modifier solution on the properties of composite membranes ...

this paper focused on the characterization of electrochemical behavior of a martensitic stainless steel inthe acidic solutions. for this purpose, electrochemical parameters were derived from potentiodynamicpolarization, mott schottky analysis and electrochemical impedance spectroscopy (eis) techniques.the potentiodynamic polarization results showed that corrosion current density of aisi 420 sta...

La2O2SO4 nanoceramic was synthesized via sol-gel method using lanthanum nitrate and thioacetamid as precursors and stearic acid as polymeric precursor. The characterization studies were conducted by X-ray diffraction, energy dispersive X-ray spectroscopy and scanning electron microscopy. The result showed that the synthesized sample belongs to monoclinic structure with the average sizes between...

this paper describes the development, electrochemical characterization and utilization of novel modified molybdenum (vi) complex-carbon nanotube paste electrode for the electrocatalytic determination of ascorbic acid (aa). the electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (cv) that showed a shift of the oxidation peak potential of aa about 235 mv ...

Electrochemical analysis allows in situ characterization of solid oxide electrochemical cells (SOCs) under operating conditions. However, the SOCs that have been analyzed in this way have ill-defined or uncommon microstructures in terms of porosity and tortuosity. Therefore, the nano-scale characterization of SOCs with respect to three-phase boundaries has been hindered. We introduce novel in s...

Materials, synthetic procedures and physical measurements. SI-­‐1 Figure S1. CV data for [(TPEN)Fe] (1). SI-­‐2 Figure S2. UV-­‐visible monitoring of the reaction of [(TPEN)Fe] (1) with dioxygen in the presence of one equivalent BPh4 and 1 equivalent HClO4 in acetonitrile at -­‐20°C. SI-­‐3 Figure S3. X-­‐band EPR spectrum at 100 K of [(TPEN)Fe(OOH)] (2) generated by reaction of 1 with 50 eq H2...

this review reports recent advances in metallic nanostructures based electrochemical sensors. interesting aspects of nps include size and shape-dependent interatomic bond distances, melting points, chemical reactivity, and optical and electronic properties. the small size of metallic nanostructures has allowed nanoscale electrochemical processes to be probed. electrochemical characteristics can...

fabrication and electrochemical characterization of a sensor for the determination of epinephrine (ep), uric acid (ua) and folic acid (fa) is described. the sensor  was prepared using carbon paste electrode (cpe) modified with 3,4-dihydroxybenzaldehyde-2,4-dinitrophenylhydrazone (ddp) and carbon nanotubes (cnts), which makes the modified electrode highly sensitive for the electrochemical detect...

This paper focused on the characterization of electrochemical behavior of a martensitic stainless steel in the acidic solutions. For this purpose, electrochemical parameters were derived from potentiodynamic polarization, Mott Schottky analysis and electrochemical impedance spectroscopy (EIS) techniques. The potentiodynamic polarization results showed that corrosion current density of AISI 420 ...