نتایج جستجو برای: Electropolymerization

تعداد نتایج: 488  

2017
Nur Afifah Zubair Norizah Abdul Rahman Hong Ngee Lim Yusran Sulaiman

Electrically conductive nanofiber is well known as an excellent nanostructured material for its outstanding performances. In this work, poly(3,4-ethylenedioxythiophene) (PEDOT)-coated polyvinyl alcohol-graphene oxide (PVA-GO)-conducting nanofibers were fabricated via a combined method using electrospinning and electropolymerization techniques. During electrospinning, the concentration of PVA-GO...

Journal: :Dalton transactions 2011
Cibely S Martin Marcos F S Teixeira

The [Mn(4)(IV)O(5)(terpy)(4)(H(2)O)(2)](6+) complex shows great potential for electrode modification by electropolymerization using cyclic voltammetry. The electropolymerization mechanism was based on the electron transfer between dx(2)-y(2) orbitals of the metallic center and pπ orbital of the ligand.

Journal: :Journal of applied physics 2009
Benjamin L Fletcher Jared T Fern Kevin Rhodes Timothy E McKnight Jason D Fowlkes Scott T Retterer David J Keffer Michael L Simpson Mitchel J Doktycz

Anode geometry can significantly affect the electrochemical synthesis of conductive polymers. Here, the effects of anode dimensions on the electropolymerization of pyrrole are investigated. Band microelectrodes were prepared with widths ranging from 2 to 500 mum. The anode dimension has a significant effect on the resulting thickness of polymer film. The electropolymerization process deviates s...

Journal: :Dalton transactions 2015
Zekeriya Biyiklioglu Huseyin Bas Hakan Alp

A novel series of axially disubstituted silicon(iv) phthalocyanines bearing electropolymerizable ligands were designed and synthesized for the first time. The silicon(iv) phthalocyanines were characterized by various spectroscopic techniques as well as elemental analysis. The aggregation behavior of the SiPcs were examined in different solvents and at different concentrations in chloroform. In ...

Journal: :The journal of physical chemistry. B 2016
Jian Xu Anthony Palumbo Wei Xu Eui-Hyeok Yang

We present a systematic study on the effects of electropolymerization parameters of polypyrrole-dodecylbenzenesulfonate (PPy(DBS)) surfaces on the flattening behaviors of organic droplets during reduction and oxidation (redox). PPy(DBS) surfaces were fabricated under varying electropolymerization conditions, including voltage, surface charge density, and dopant electrolyte (DBS-) concentration....

2007
Guang Li You Wang Hui Xu

A disposable amperometric biosensor for commercial use to detect hydrogen peroxide has been developed. The sensor is based on screen-printed carbon paste electrodes modified by electropolymerization of pyrrole with horseradish peroxidase (HRP) entrapped. The facture techniques of fabricating the enzyme electrodes are suitable for mass production and quality control. The biosensor shows a linear...

Journal: :Bioresource technology 2012
Huijuan Liu Jianbo Guo Jiuhui Qu Jing Lian Yankai Guo William Jefferson Jingliang Yang

Electropolymerization biocarriers were prepared by the electropolymerization of polypyrrole (PPy) on an active carbon felt (ACF) electrode using doping anions anthraquinone-2-sulfonate (AQS) or Na(2)SO(4). The functional electropolymerization biocarrier (ACF/PPy/AQS) with AQS was used as an immobilized redox mediator for the denitrification process. The characteristics of the electropolymerizat...

Journal: :Dalton transactions 2016
Zekeriya Biyiklioglu Hakan Alp

The treatment of boron(III) subphthalocyanine chloride with 1,3-bis[3-(diethylamino)phenoxy]propan-2-ol 2 and 2,3-bis[3-(diethylamino)phenoxy]propan-1-ol 4 in toluene gave the corresponding axially substituted boron(III) subphthalocyanine compounds 3 and 5. The novel axially diethylaminophenoxypropanoxy substituted subphthalocyanines were characterized by standard spectroscopy methods. The elec...

2006
Miao Yuqing

The glucose biosensors were prepared by the electropolymerization of the non-conductive polymer, Poly(o-phenylenediamine), onto a planar screen-printed electrode. A fabrication procedure was performed to decrease the waste of expensive enzyme. The amperometric glucose response was measured by the potensiostating of the prepared glucose biosensors at a potential of 0.3 V with ferrocene as mediat...

Journal: :The Journal of Physical Chemistry C 2020

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