Exothermic or heated processes create potentially unsafe work environments for an estimated 5-10 million American workers each year. Excessive heat and process contaminants have the potential to cause acute health effects such as heat stroke, and chronic effects such as manganism in welders. Although millions of workers are exposed to exothermic processes, insufficient attention has been given ...

The polymerization of resin adhesives, which is highly nonlinear, is chosen as a control process in this paper. When phenol and formaldehyde are mixed, a sudden and unpredictable heat is produced due to an exothermic reaction, which could cause the deviation of process temperature and hence diminish the product quality. Therefore, temperature control is necessitated for exothermic batch reactor...

The solid state thermochemical decomposition kinetics and activation energy of neat 1,3,5,5-tetranitrohexahydropyrimidine (DNNC) and its DNNC-d6 deuterium labeled analogue were obtained by isothermal differential scanning calorimetry (IDSC) at 142, 145, and 148 ◦C. Global rate constants and kinetic deuterium isotope effect (KDIE) data from the exothermic decomposition process suggest that homol...

The aim of this research is to control the reactor temperature of an exothermic batch process. During the process, large amount of heat will be released rapidly when the reactants are mixed together. The exothermic behaviour causes the reaction to become unstable and consequently poses safety concern to the plant personnel. In practice, heat is needed to speed up the reaction rate so that the o...

The polymerization of resin adhesives, which is highly nonlinear, is chosen as a process control system. When phenol and formaldehyde are mixed, a sudden and unpredictable heat is produced due to an exothermic reaction, which could cause the deviation of process temperature and hence diminish the product quality. Hence, temperature control is necessary for exothermic batch reactor. The most com...

The paper presents some different methods for a chemical exothermic batch reactor control. A mathematical model including reaction kinetics was used to simulate a real process. The process chemical reaction is strongly exothermic so the in-reactor temperature is rising very fast due to reaction component dosing. Thus, the temperature control is necessary. The system is nonlinear because of chem...

In previous papers we have demonstrated how the direct simulation Monte Carlo method can be used to simulate detonations. Those simulations were limited to exothermic reactions. In this paper exothermic and endothermic reactions are simulated. Under these circumstances, one obtains pathological detonations. That is, these simulations cannot be predicted using the well-known Chapman-Jouguet hypo...

The exothermic continuous stirred tank reactor (CSTR) is a classical yet complex case study of nonlinear dynamical systems. Power-shaping control is a recent approach for the control of nonlinear systems based on the physics of the dynamical system. In this paper we present a general methodology to apply the power-shaping control approach to the exothermic CSTR study case. It results in a globa...

In the conducted investigations, aluminium dross, i.e. solid waste formed in the production and recycling of aluminium, was used as one of the basic raw materials to obtain a material characterised by insulating and exothermic properties, applied to heat riser heads in the process of iron or steel casting. The product was obtained by filtrating the slurry. In the raw mix, aluminium dross played...