Fe-doped titanite (TiCaSiO5) and quasi-titanite (Ti0.5CaSi1.5O5) compositions were synthesized by the ceramic method. For each structure, two samples with 0.1 mol% and 0.2 mol% Fe were used. The synthesized samples were homogenized using a planetary ball mill in 2-ethylhexyl stearate solvent and then printed on the ceramic with screen printing system....

Introduction: Numerous studies over the past decade have demonstrated that microbial life rapidly colonizes terrestrial subaqueous volcanic glass [1-5]. Evidence for microbial alteration of terrestrial subaqueous volcanic rocks has been reported from modern ocean crust, ophiolites, and Archean greenstone belts [1-5]. Microbial alteration structures with characteristic granular and tubular morph...

We evaluated the inducibility of nitrate-dependent Fe(II)-EDTA oxidation (NDFO) in non-growth, chloramphenicol-amended, resting-cell suspensions of Dechloromonas sp. strain UWNR4 and Acidovorax sp. strain 2AN. Cells previously incubated with Fe(II)-EDTA oxidized ca. 6-fold more Fe(II)-EDTA than cells previously incubated with Fe(III)-EDTA. This is the first report of induction of NDFO by Fe(II).

Titanite (CaTiSiO5) is a naturally occurring silicate phase, recently recognised as potential material for immobilization of nuclear wastes, high-end ceramic lining and optical device development. The undergoes pressure-induced structural transition (P21/c to C2/c) at ~3.5 GPa, which we confirm from density function perturbation theory. Using first principles calculations pressure-dependent par...

The Dirac spin liquid ground state of the spin 1/2 Heisenberg kagome antiferromagnet has potential instabilities. This has been suggested as the reason why it does not emerge as the ground state in large-scale numerical calculations. However, previous attempts to observe these instabilities have failed. We report on the discovery of a projected BCS state with lower energy than the projected Dir...

Using structure-directing agents, pore space partitions of a Zn-phosphonocarboxylate framework have been achieved. Selective adsorption of CO(2) over N(2) has been greatly improved from ca. 9 : 1 to 94 : 1.