نتایج جستجو برای: Hierarchical zeolites

تعداد نتایج: 96710  

Journal: :Chemical communications 2009
Dong-Hwan Lee Minkee Choi Byung-Woo Yu Ryong Ryoo

Mesopore walls of hierarchically meso-/microporous zeolites (MFI, BEA and LTA) are covered with silanol groups, so that the zeolites can be functionalized with various organic groups via silylation; the organic-functionalized hierarchical zeolites exhibit hydrothermal stability and reusability in catalytic applications, as compared with organic-functionalized mesoporous silica.

Journal: :ChemSusChem 2014
Danny Verboekend Javier Pérez-Ramírez

Hierarchical zeolites have been established as a superior type of aluminosilicate catalysts compared to their conventional (purely microporous) counterparts. An impressive array of bottom-up and top-down approaches has been developed during the last decade to design and subsequently exploit these exciting materials catalytically. However, the sustainability of the developed synthetic methods ha...

Journal: :Chemical Society reviews 2015
Ying Wei Tanja E Parmentier Krijn P de Jong Jovana Zečević

Recently the concept of hierarchical zeolites invoked more explicit attention to enhanced accessibility of zeolites. By realizing additional meso-/macroporosity with the intrinsic microporosity of zeolites, a hierarchical pore system arises which facilitates mass transport while maintaining the zeolite shape selectivity. A great number of synthesis strategies have been developed for tailoring t...

Journal: :Chemical communications 2016
Ning Wang Weizhong Qian Kui Shen Chang Su Fei Wei

Unique bayberry-like MFI zeolites are synthesized through a quasi-solid-state crystallization approach. This hierarchical zeolite structure has a relatively thick shell, densely grown nanocrystals with an ordered packed channel, high mechanical stability, high surface area and a low Si/Al ratio. Its catalytic efficiency for methanol-to-aromatics is significantly higher than that of conventional...

2016
Xuan Hoan Vu Udo Armbruster Andreas Martin

Micro/mesoporous zeolitic composites (MZCs) represent an important class of hierarchical zeolitic materials that have attracted increasing attention in recent years. By introducing an additional mesoporous phase interconnected with the microporosity of zeolites, a hierarchical porous system of MZCs is formed which facilitates molecular transport while preserving the intrinsic catalytic properti...

2016
Chao Li Hong Je Cho Zhuopeng Wang Jinsheng Gou Yanqun Ren Hongxia Xi Wei Fan

Zeolites are crystalline inorganic porous materials formed by TO4 tetrahedra (T=Si, Al, P, etc.) with ordered microporous structures. As a result of their tunable acidities and framework structures, zeolites have been used widely in catalysis and molecular adsorption/separation as well as several other emerging applications. However, the pore size of a zeolite is usually smaller than 2 nm, whic...

Journal: :Chemical Society reviews 2015
Jiyang Li Avelino Corma Jihong Yu

The search for new zeolites is of continuous interest in the field of zeolite science because of their widespread application in catalysis and adsorption-separation. To this end, considerable efforts have been devoted to the preparation of new zeolites with novel porous architectures and compositions. Taking account of the key factors governing the formation of zeolites (e.g., guest species, fr...

2016
Danny Verboekend Tobias C. Keller Maria Milina Roland Hauert Javier Pérez-Ramírez

Hierarchical clinoptilolite and L zeolites are prepared using optimized tandem dealumination-desilication treatments. The main challenge in the post-synthetic modification of these zeolites is the high Al content, requiring a tailored dealumination prior to the desilication step. For natural clinoptilolite sequential acid treatments using aqueous HCl solutions were applied, while for L a contro...

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