In this study, the hydrogen permeation in the supercooled liquid state for Ni65Nb25Zr10, Ni60Nb20Zr20 and Ni55Nb15Zr30 metallic glasses was investigated in conjunction with the discussion on the effect of hydrogen diffusion on hydrogen permeation. The hydrogen permeation of the Ni65Nb25Zr10 and Ni60Nb20Zr20 metallic glasses increases significantly by the transition from the glassy solid state t...

A palladium membrane was prepared using the electroless plating technique (ELP) for the separation and purification of hydrogen from a gas mixture. Depending on operating conditions, hydrogen flux from the membrane was in the range of 0.012-0.023 mol.m-2.s-1. The membrane performance in the presence of CO2 was investigated. The results of the GC analysis showed that at a feed concentration of 1...

The absorption and permeation of hydrogen in metals occurs in a variety of technological processes and systems, and in some cases the results are extremely detrimental (e. g., hydrogen embrittlement, stress corrosion, degradation of electrical and magnetic properties, undesired loss (or gain) of hydrogen, etc.). In an increasing number of applications the hydrogen pressure, p, is extremely low,...

Palladium-based membranes are attractive for their nearly perfect permselectivity to hydrogen. Membrane modules, consisting of a membrane foil, porous stainless steel substrate, test frame and flange were assembled and tested in an electrically heated vessel. Instantaneous hydrogen permeation flux was measured. Influences of operation conditions on the membrane performance were examined. Micros...

Various effects induced by self-stress during hydrogen diffusion across metallic tabular membranes are discussed. The up-hill diffusion in the initial time of permeation, the time course of inner pressure change, the steady distributions of hydrogen concentration and residual stress in membranes, and the acceleration of permeation rate on interruption of hydrogen charging are properly interpret...

the aim of the present study was to investigate the relationship between the polar surface area and other molecular properties of the model drugs and their transdermal permeability across the rat skin. few model drugs which are weakly acidic (ibuprofen, aceclofenac and glipizide) and weakly basic (olanzapine, telmisartan and sildenafil citrate) were selected for the study based on polar surface...

a palladium composite membrane was prepared by electroless plating on oxidized porous stainless steel support (ox-pss). hydrogen permeation flux through this composite membrane was measured in the temperature range of 574-674k and the pressure difference of two sides of membrane up to 90kpa. a simplified resistance model was employed to analyze the permeation behavior of hydrogen through pd/ox-...

A palladium composite membrane was prepared by electroless plating on oxidized porous stainless steel support (ox-PSS). Hydrogen permeation flux through this composite membrane was measured in the temperature range of 574-674K and the pressure difference of two sides of membrane up to 90kPa. A simplified resistance model was employed to analyze the permeation behavior of hydrogen through Pd/ox-...

A mixed proton–electron conducting perovskite was synthesized by liquid-citrate method and the corresponding membrane was prepared by pressing followed by sintering. The hydrogen permeability of BaCe0.9Yb0.1O3-δ was studied as a function of temperature and hydrogen partial pressure (PH2) gradient. Using 100% dry hydrogen at 1173 K, the hydrogen permeation rate of dense membranes (1.63 mm thick)...