نتایج جستجو برای: Imines

تعداد نتایج: 2655  

Journal: :iranian chemical communication 0
gholamhassan imanzadeh department of chemistry, college of basic science, university of mohaghegh ardabili 56199-11367, ardabil, iran hamideh vakili department of chemistry, college of basic science, university of mohaghegh ardabili 56199-11367, ardabil, iran

a simple, efficient and clean procedure has been developed for the cleavage of imines c=n bond. deprotection of imines to their parent carbonyl and amine compounds was achieved using p-toluenesulfonic acid in the solid state condition at 25-45 ˚c. the salient features of this methodology are shorter reaction times, cheap processing, high yields of product and easy availability of the catalyst. ...

A simple, efficient and clean procedure has been developed for the cleavage of imines C=N bond. Deprotection of imines to their parent carbonyl and amine compounds was achieved using p-toluenesulfonic acid in the solid state condition at 25-45 ˚C. The salient features of this methodology are shorter reaction times, cheap processing, high yields of product and easy availability of the catalyst. ...

Journal: :Cancer research 1987
G Powis E M Hodnett K S Santone K L See D C Melder

Quinone(di)imines are nitrogen analogues of quinones in which one or both quinone oxygens are replaced by an imino group. A series of quinone(di)imines with antitumor activity has been studied for its in vitro chemical reactivity, metabolism, acute toxicity to primary cultured rat hepatocytes, and growth-inhibitory activity with Chinese hamster ovary (CHO) cells. The quinone(di)imines exhibited...

Journal: :Chemical communications 2015
Guorong Sheng Kai Huang Shicong Ma Jing Qian Ping Lu Yanguang Wang

The rhodium-catalyzed reactions of 3-diazoindolin-2-imines with N,N-dialkylanilines, N-allyl-N-alkylanilines, and N-propargyl-N-alkylanilines and 3-diazoindolin-2-imines furnished 3-aryl-2-aminoindoles, 3-allyl-3-amino-2-iminoindolines, and tetrahydro-[1,4]diazepino[2,3-b]indoles, respectively. 3-Diazoindolin-2-imines acted as precursors of α-imino rhodium carbenes in these transformations.

Journal: :Journal of the American Chemical Society 2014
Ming Wang Zhijian Huang Jianfeng Xu Yonggui Robin Chi

The first N-heterocyclic carbene (NHC)-catalyzed [3+4] cycloaddition of azomethine imines and enals is disclosed. Oxidative catalytic remote activation of enals affords 1,4-dipolarophile intermediates that react with 1,3-dipolar azomethine imines to generate dinitrogen-fused seven-membered heterocyclic products with high optical purities. Our approach also provides effective kinetic resolution ...

Journal: :Journal of the American Chemical Society 2011
Li Huang William D Wulff

A method is described which provides for the direct asymmetric catalytic synthesis of trisubstituted aziridines from imines and diazo compounds. While unactivated imines were not reactive to α-diazo carbonyl compounds in which the diazo carbon was disubstituted, N-Boc imines react with both α-diazo esters and α-diazo-N-acyloxazolidinones to give trisubstituted aziridines with excellent diastere...

Journal: :Chemical communications 2014
Taku Kitanosono Pengyu Xu Satoshi Isshiki Lei Zhu Shū Kobayashi

Enantioselective conjugate addition of bis(pinacolato)diboron to α,β-unsaturated imines proceeds smoothly in water in the presence of a chiral copper(II) complex consisting of Cu(OAc)2 and chiral 2,2'-bipyridine. The corresponding β-boryl imines, which were oxidized to β-hydroxy imines, further leading to γ-amino alcohols, were obtained in high yields and high enantioselectivities.

2006
Garth Powis Ernest M. Hodnett Kenneth S. Santone Kevin Lee Deborah C. Melder

Quinone(di)iinines are nitrogen analogues of quiñonesin which one or both quinone oxygens are replaced by an ¡minogroup. A series of quinone(di)imines with antitumor activity has been studied for its in vitro chemical reactivity, metabolism, acute toxicity to primary cultured rat hepatocytes, and growth-inhibitory activity with Chinese hamster ovary (CHO) cells. The quinone(di)iniines exhibit...

Journal: :Journal of the American Chemical Society 2005
Kristine A Nolin Richard W Ahn F Dean Toste

An air- and moisture-tolerant enantioselective hydrosilylation of N-phosphinyl imines employing a chiral Re(V)-oxo complex as a catalyst is described. The chiral catalyst is a cyanobis(oxazoline) (CNbox)-ligated rhenium-oxo complex of the general formula (CNbox)Re(O)Cl2(OPPh3). Using this catalyst, a wide range of aromatic imines (including cyclic, acyclic, and heteroaromatic), alpha-iminoester...

Journal: :Organic letters 2007
Jordi Burés Carles Isart Jaume Vilarrasa

As N-sulfenyl imines (e.g., RR'C=N-SAr) can be readily transformed to their N-sulfinyl imines (RR'C=N-SOAr), N-sulfonyl imines (RR'C=N-SO2Ar), and N-sulfonyl oxaziridines, the very mild procedure developed to convert ketoximes and secondary nitro derivatives to N-arenesulfenyl ketimines constitutes a new and efficient route to all these series of compounds. The configuration of the alpha-stereo...

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