the nitrite ® nitro isomerization in nitritopentaamine cobalt (iii) halides has been known. in this paper, the effect of the size of the counter ions (noncoordinated groups) on the rate of isomerization in nitritopentaamine cobalt (iii) halides, is reported. the rate of isomerization is decreased by increasing the size of the counter ions. this decrease is explained on the basis of steric inter...

The nitrite ® nitro isomerization in nitritopentaamine cobalt (III) halides has been known. In this paper, the effect of the size of the counter ions (noncoordinated groups) on the rate of isomerization in nitritopentaamine cobalt (III) halides, is reported. The rate of isomerization is decreased by increasing the size of the counter ions. This decrease is explained on the...

in this research project, the nitrito nitro isomerization of [co (nh3)5no2]f2 complex has been studied. isomerization of this complex in the solid state follows a first order kinetics. the rate of isomerization at different temperatures was determined using a fourier transform lnfrared spectrophotometer. ? and ? are calculated at 298 k. the infrared, visible and ultraviolet spectra of this comp...

In this research project, the nitrito nitro isomerization of [Co (NH3)5No2]F2 complex has been studied. Isomerization of this complex in the solid state follows a first order kinetics. The rate of isomerization at different temperatures was determined using a Fourier Transform Lnfrared Spectrophotometer. ? and ? are calculated at 298 K. The infrared, visible and ultraviolet spectra of th...

Catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. Using Michaelis-Menten equation and Haldane relationship, the main kinetic parameters were determined: Kmf, Vmf, Kmr, Vmr. By comparing the aqueous-ethanol medium with an aqueous solution, the measured values of Kmr and Kmf were increased in the aqueous-ethanol solution, whi...

Catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. Using Michaelis-Menten equation and Haldane relationship, the main kinetic parameters were determined: Kmf, Vmf, Kmr, Vmr. By comparing the aqueous-ethanol medium with an aqueous solution, the measured values of Kmr and Kmf were increased in the aqueous-ethanol solution, whi...

Membrane environment and fluidity can modulate the dynamics and interactions of membrane proteins and can thereby strongly influence the function of cells and organisms in general. In this work, we demonstrate that trans-cis isomerization of lipophilic dyes is a useful parameter to monitor packaging and fluidity of biomembranes. Fluorescence fluctuations, generated by trans-cis isomerization of...

catalytic isomerization of glucose to fructose by immobilized glucose isomerase in an aqueous-ethanol medium was studied. using michaelis-menten equation and haldane relationship, the main kinetic parameters were determined: kmf, vmf, kmr, vmr. by comparing the aqueous-ethanol medium with an aqueous solution, the measured values of kmr and kmf were increased in the aqueous-ethanol solution, whi...

Cat’s claw oxindole alkaloids are prone to isomerization in aqueous solution. However, studies on their behavior in extraction processes are scarce. This paper addressed the issue by considering five commonly used extraction processes. Unlike dynamic maceration (DM) and ultrasound-assisted extraction, substantial isomerization was induced by static maceration, turbo-extraction and reflux extrac...